郝凤霞^,,
田梅,
房俊卓,
齐之锴,
杨金会
宁夏大学省部共建煤炭高效利用与绿色化工国家重点实验室, 银川 750021

作者简介: 郝凤霞(1978-),女,硕士,副教授,研究方向为农药环境污染防治,E-mail:hao_fx@nxu.edu.cn.

通讯作者: 郝凤霞,hao_fx@nxu.edu.cn ;

基金项目: 国家自然科学基金资助项目（21567022）


中图分类号: X171.5

Study on Residue and Degradation of Tsumacide in Lycium barbarum and Soil

Hao Fengxia^,,
Tian Mei,
Fang Junzhuo,
Qi Zhikai,
Yang Jinhui
State Key Laboratory of High-efficiency Utilization of Coal & Green Chemical Engineering, Ningxia University, Yinchuan 750021, China

Corresponding author: Hao Fengxia,hao_fx@nxu.edu.cn ;

CLC number: X171.5

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摘要:速灭威是枸杞中常用的一种氨基甲酸酯类农药，在防治枸杞蚜虫的同时，残留在枸杞和土壤中的农药又会对生态环境造成危害。通过田间试验，研究了速灭威在枸杞和土壤中的残留与消解动态。结果表明，速灭威在枸杞和土壤中的半衰期分别为3.38 d和5.29 d。将25%速灭威可湿性粉剂以750 g·hm^-2和1 500 g·hm^-2剂量在枸杞上施药，喷施药2~3次，施药间隔期7 d，距最后一次施药21 d，速灭威在枸杞和土壤中的最大残留量分别为0.0485 mg·kg^-1和0.1596 mg·kg^-1。建议速灭威在枸杞上的最大允许残留限量为0.05 mg·kg^-1，施药安全间隔期为21 d。
关键词: 速灭威/
枸杞/
土壤/
消解动态/
最终残留

Abstract:Tsumacide is a commom carbamate pesticide for controlling Aphis sp., but meantime, pesticide residues in Lycium barbarum and soil will cause harm to ecological environment. Field experiments were conducted to study the residues and degradation of tsumacide in Lycium barbarum and soil in Ningxia. As a result, the half life of tsumacide in Lycium barbarum and soil was 3.38 d and 5.29 d respectively. When spaying 2~3 times with the recommended dosages of 750 g·hm^-2 and 1 500 g·hm^-2, the final maximum residue levels (MRL) of tsumacide in Lycium barbarum and soil were 0.0485 mg·kg^-1 and 0.1596 mg·kg^-1 at 21 d after the last application, respectively. It is suggested that the maximum permissible residue limit of tsumacide in Lycium barbarum is 0.05 mg·kg^-1, and the safe interval period is 21 d.
Key words:tsumacide/
Lycium barbarum/
soil/
dynamic degradation/
residue.

高希武, 郭艳春, 王恒亮. 新编实用农药手册[M]. 郑州:中原农民出版社, 2002:157-159

张奇, 李铁军, 朱晓霞, 等. 氨基甲酸酯类杀虫剂速灭威酶联免疫吸附分析方法研究[J]. 分析化学, 2006, 34(2):178-182Zhang Q, Li T J, Zhu X X, et al. Determination of N-methylcarbamate insecticide metolcarb by enzyme-linked immunosorbent assay[J]. Chinese Journal of Analytical Chemistry, 2006, 34(2):178-182(in Chinese)

刘菲菲, 赵成林, 朱国念. 超高效液相色谱-串联质谱法检测水稻及稻田环境中速灭威的残留灭威的残留[J]. 农药学学报, 2013, 15(4):445-450Liu F F, Zhao C L, Zhu G N. Determination of metolcarb residue in rice and paddy field by ultra high performance liquid chromatography tandem mass spectrometry[J]. Chinese Journal of Pesticide Science, 2013, 15(4):445-450(in Chinese)

汤轶伟, 高子媛, 魏立巧, 等. 食品中速灭威农药残留检测方法研究进展[J]. 食品安全质量检测学报, 2014, 5(3):846-852Tang Y W, Gao Z Y, Wei L Q, et al. Research progress of detecting methods of metolcarb in food[J]. Journal of Food Safety and Quality, 2014, 5(3):846-852(in Chinese)

郝凤霞, 李学晴, 齐瑾, 等. MSPD-HPLC同时测定枸杞中3种氨基甲酸酯类农药[J]. 农药, 2015, 54(7):525-527Hao F X, Li X Q, Qi J, et al. Simultaneous determination of three carbamate pesticides in Fructus lycii by MSPD-HPLC[J]. Agrochemicals, 2015, 54(7):525-527(in Chinese)

田甜, 邵康群. 常见水果中8种氨基甲酸酯农药的测定[J]. 现代农业科技, 2018(11):117-119 Tian T, Shao K Q. Determination of 8kinds of carbamate pesticides in common fruits[J]. Modern Agricultural Science and Technology, 2018(11):117-119(in Chinese)

刘菲菲, 赵成林, 朱国念. 超高效液相色谱-串联质谱法检测水稻及稻田环境中速灭威的残留[J]. 农药学学报, 2013, 15(4):445-450Liu F F, Zhao C L, Zhu G N. Determination of metolcarb residue in rice and paddy field by ultra high performance liquid chromatography tandem mass spectrometry[J]. Chinese Journal of Pesticide Science, 2013, 15(4):445-450(in Chinese)

黄霞, 刘芳, 聂立, 等. 高效液相色谱法测定牛奶中速灭威、克百威、异丙威农药残留[J]. 中国酿造, 2017, 36(1):168-170Huang X, Liu F, Nie L, et al. Determination of metolcarb, carbofuran and isoprocarb contents in milk by HPLC[J]. China Brewing, 2017, 36(1):168-170(in Chinese)

刘礼亲, 周桂凤. 杀虫双、速灭威混配对小鼠全血胆碱酯酶活性的影响[J]. 湖南师范大学学报:医学版, 2011, 8(1):90-93Liu L Q, Zhou G F. Influence of cholinesterase activities in whole blood mixing with bisultap and metolcarb[J]. Journal of Hunan Normal University:Medical Science, 2011, 8(1):90-93(in Chinese)

张艳, 王取南, 杨叶新. 速灭威对N2a成神经元细胞、C6胶质细胞及小鼠胚胎神经干细胞增殖的影响[J]. 安徽医科大学学报, 2009, 44(4):453-457Zhang Y, Wang Q N, Yang Y X. Effect of m-tolyl methylcarbamate on cell proliferation of mouse neuroblastoma (N2a) cell, C6 glioma cell and mouse embryonic neural stem cell[J]. Acta Universitatis Medicinalis Anhui, 2009, 44(4):453-457(in Chinese)

吴永梅, 殷明, 张德兵, 等. 吡蚜酮及其复配剂对稻飞虱的防治效果研究[J]. 现代农业科技, 2016(18):102,105 Wu Y M, Yin M, Zhang D B, et al. Study on the control effect of pymetrozine and its compound on rice planthopper[J]. Modern Agricultural Science and Technology, 2016(18):102,105(in Chinese)

王会福, 陈伟强. 25%噻嗪·速灭威WP防治稻飞虱药效试验初报[J]. 现代农药, 2009, 8(1):55-56Wang H F, Chen W Q. Preliminary report of 25% thiazine-tsumacide WP against rice planthopper[J]. Modern Agrochemicals, 2009, 8(1):55-56(in Chinese)

张千, 王取南, 夏玉宝, 等. 出生后早期接触速灭威对小鼠空间学习记忆能力的影响[J]. 中华疾病控制杂志, 2009, 13(3):350-354Zhang Q, Wang Q N, Xia Y B, et al. Effects of early postnatal exposure to m-tolyl methylcarbamate on spatial learning and memory ability of mice[J]. Chinese Journal of Disease Control and Prevention, 2009, 13(3):350-354(in Chinese)

陆贻通, 樊德方. 水中速灭威农药非生物降解的研究[J]. 环境化学, 1984, 3(5):48-54Lu Y T, Fan D F. Study on non-biodegradation of metolcarb pesticide in water[J]. Environmental Chemistry, 1984, 3(5):48-54(in Chinese)

郝凤霞, 谢青, 夏维涛, 等. 速灭威在几种枸杞土壤中的吸附及解吸行为研究[J]. 生态环境学报, 2018, 27(1):144-149Hao F X, Xie Q, Xia W T, et al. Study on adsorption and desorption of MTMC on several soils in Lycium barbarum field[J]. Ecology and Environmental Sciences, 2018, 27(1):144-149(in Chinese)

中华人民共和国农业农村部. NY/T 788-2018农作物中农药残留试验准则[S]. 北京:中国农业出版社, 2018 Ministry of Agriculture and Rural Affairs of the People's Republic of China. NY/T 788-2018 Guideline for the testing of pesticide residues in crops[S]. Beijing:China Agricultural Press, 2018(in Chinese)

农业部农药检定所. 农药登记残留田间试验标准操作规程[M]. 北京:中国标准出版社, 2007:3-10

蔡道基. 农药环境毒理学研究[M]. 北京:中国环境科学出版社, 1999:219

中华人民共和国国家卫生和计划生育委员会,中华人民共和国农业部,国家食品药品监督管理总局. GB2763-2016食品国家安全标准食品中农药最大残留限量[S]. 北京:中国农业出版社, 2016

王洪涛, 许志强, 张玉芳. 涕灭威在苹果和土壤中的残留试验研究[J]. 农药, 2002, 41(2):19-21Wang H T, Xu Z Q, Zhang Y F. Studies on the residue of aldicarb in apple and soil[J]. Agrochemicals, 2002, 41(2):19-21(in Chinese)

曹爱华, 刘保安, 徐光军, 等. 涕灭威颗粒剂在烟草及土壤中残留消解动态和安全使用标准的研究[J]. 中国烟草, 1996, 17(3):26-30

闫亚杰. 抗蚜威和异丙威残留降解动态研究[D]. 兰州:甘肃农业大学, 2004:26 Yan Y J. The residue and dynamic degradation of pirimicarb and isoprocarb[D]. Lanzhou:Gansu Agricultural University, 2004:26(in Chinese)

阳承虎, 欧晓明, 刘红玉, 等. 新农药氯溴虫腈在甘蓝和土壤中的残留及持久性[J].农业环境科学学报, 2014, 33(5):875-881Yang C H, Ou X M, Liu H Y, et al. Residues and persistence of novel insecticide HNPC-A3061 in Chinese cabbages and soils[J]. Journal of Agro-Environment Science, 2014, 33(5):875-881(in Chinese)