张丽丽,
于洋,
牛文凤,
林军,
郑玉婷^,
生态环境部固体废物与化学品管理技术中心, 北京 100029

作者简介: 张丽丽(1992-),女,硕士,研究方向为化学品环境风险评估,E-mail:zhanglili@meescc.cn.

通讯作者: 郑玉婷,zhengyuting@meescc.cn

基金项目: 国家重点研发计划项目（2017YFD0800701）


中图分类号: X171.5

Ecological Risk and Management Measures of High Yield Chemical N,N-dimethylformamide

Zhang Lili,
Yu Yang,
Niu Wenfeng,
Lin Jun,
Zheng Yuting^,
Solid Waste and Chemicals Management Center, Ministry of Ecology and Environment, Beijing 100029, China

Corresponding author: Zheng Yuting,zhengyuting@meescc.cn

CLC number: X171.5

-->

摘要
HTML全文
图(0)表(0)
参考文献(44)
相关文章
施引文献
资源附件(0)
访问统计

摘要:N，N-二甲基甲酰胺（N，N-dimethylformamide，DMF）是一种广泛应用于多个行业的优良溶剂，属于高产量化学品，且具有潜在的环境持久性和毒性。为明确DMF的生态环境风险并完善管控措施，本研究评估了DMF的生态环境风险，综述了我国以及发达国家对DMF的法规、标准和限量要求，分析了我国现行管控措施的不足，提出了相关建议，以期为我国DMF纳入名录管控、研究制定相关标准和完善风险管理措施等提供依据。
关键词: N,N-二甲基甲酰胺/
风险评估/
管控措施

Abstract:N,N-dimethylformamide (DMF) is an excellent solvent widely used in many industries. It is a high-yield chemical with potential environmental persistence and toxicity. In order to clarify the ecological risk of DMF and improve the control measures, this study assessed the ecological risk of DMF, summarized the regulations, standards and limitation requirements of DMF in China and developed countries, analyzed the deficiencies of current control measures in China, and put forward relevant suggestions. This study can provide a basis for the inclusion of DMF in the list control, the establishment of relevant standards, and the improvement of risk management measures.
Key words:N,N-dimethylformamide/
risk assessment/
management measures.

刘兴泉, 唐毅, 戴汉松, 等. N,N-二甲基甲酰胺的生产与应用[J]. 化工科技, 2002, 10(1):46-49Liu X Q, Tang Y, Dai H S, et al. Production and application of N,N-dimethyl formamide[J]. Chemical Science and Technology, 2002, 10(1):46-49(in Chinese)

Swedish Chemicals Agency. Proposal for identification of a substance as a Category 1A or 1B CMR, PBT, vPvB or a substance of an equivalent level of concern N,N-dimethylformamide[R]. Sundbyberg:Swedish Chemicals Agency, 2012

Environment Canada. Priority substances list assessment report N,N-dimethylformamide[R]. Quebec:Environment Canada, 2001

杨磊. DMF合成革废水综合处理工艺研究[D]. 上海:华东理工大学, 2013:1-2 Yang L. Research on process of integrated treatment of synthetic leather wastewater containing DMF[D]. Shanghai:East China University of Science and Technology, 2013:1-2(in Chinese)

魏玉梅. 二甲基甲酰胺(DMF)人群暴露评估及其健康风险的研究[D]. 杭州:浙江大学, 2011:8-9 Wei Y M. Population exposure and healthy risk of N,N-dimethylformamide (DMF)[D]. Hangzhou:Zhejiang University, 2011:8-9(in Chinese)

程弯. 纺织品中N,N-二甲基甲酰胺与N,N-二甲基乙酰胺检测方法研究[D]. 上海:东华大学, 2016:3-4 Cheng W. Study of the detection methods for N,N-dimethyl formamide and N,N-dimethyl acetamide in textile[D]. Shanghai:Donghua University, 2016:3-4(in Chinese)

Kong Z, Li L, Kurihara R, et al. Anaerobic treatment of N, N-dimethylformamide-containing wastewater by co-culturing two sources of inoculum[J]. Water Research, 2018, 139:228-239

Organization for Economic Co-operation and Development (OECD). Dimethylformamide[R]. Paris:OECD, 2003

中华人民共和国安全监管总局办公厅. 危险化学品分类信息表. (2015-09-02). https://www.mem.gov.cn/gk/gwgg/xgxywj/wxhxp_228/201509/t20150902_232638.shtml

Organization for Economic Co-operation and Development. The global portal to information on chemical substances.. https://www.echemportal.org/echemportal/substancesearch/cnlsearch_execute.action

Organization for Economic Co-operation and Development. The global portal to information on chemical substances (N,N-Dimethylformamide).. https://www.nite.go.jp/chem/english/ghs/08-mhlw-2041e.html

Moorman W J, Ahlers H W, Chapin R E, et al. Prioritization of NTP reproductive toxicants for field studies[J]. Reproductive Toxicology, 2000, 14(4):293-301

杜英英, 史福霞, 周丽佳, 等. 鞋类产品二甲基甲酰胺残留量的测定及其风险评估[J]. 皮革与化工, 2017, 34(2):17-20Du Y Y, Shi F X, Zhou L J, et al. Determination and risk assessment of dimethyl formamide contents in footwear[J]. Leather and Chemical, 2017, 34(2):17-20(in Chinese)

蒋涛, 童建. 常州市合成革面料加工企业工人健康调查[J]. 智慧健康, 2017, 3(15):117-119Jiang T, Tong J. Workers' health survey of synthetic leather fabrics processing enterprises in Changzhou[J]. Smart Healthcare, 2017, 3(15):117-119(in Chinese)

The European Parliament and the Council of the European Union. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC.. https://eur-lex.europa.eu/legal-content/EN/TXT/?qid=1572400051792&uri=CELEX:32006R1907

United States Environmental Protection Agency. Initial list of hazardous air pollutants with modifications.. https://www.epa.gov/haps/initial-list-hazardous-air-pollutants-modifications

李嘉琦. 基于风险评估原理筛选我国优先控制有毒有害大气污染物方法研究[D]. 沈阳:沈阳农业大学, 2019:22-23 Li J Q. Study on the method of priority control for hazardous air pollutants in China based on risk assessment[D]. Shenyang:Shenyang Agricultural University, 2019:22-23(in Chinese)

Environment and Climate Change Canada. Second priority substances list (PSL2).. http://www.ec.gc.ca/ese-ees/default.asp?lang=En&n=C04CA116-1

International Association for Research and Testing in the Field of Textile and Leather Ecology. Leather Standard by OEKO-TEX®[R]. Zurich:International Association for Research and Testing in the Field of Textile and Leather Ecology, 2019

International Association for Research and Testing in the Field of Textile and Leather Ecology. Standard 100 by OEKO-TEX®[R]. Zurich:International Association for Research and Testing in the Field of Textile and Leather Ecology, 2019

Chemicals Evaluation and Research Institute (CERI). Hazard assessment report N,N-Dimethylformamide[R]. Tokyo:CERI, 2007

肖继波, 张立钦, 曹玉成. 温州北山河黑臭河水治理工程[J]. 中国给水排水, 2007, 23(12):51-53Xiao J B, Zhang L Q, Cao Y C. Treatment project for heavy polluted water of Beishan River in Wenzhou[J]. China Water & Wastewater, 2007, 23(12):51-53(in Chinese)

王逸虹, 顾海东, 朱仁康. 环境样品中N,N-二甲基甲酰胺的监测[J]. 甘肃环境研究与监测, 2002, 15(4):256-257

周华芬. 浙江某地区合成革行业DMF污染监测评估及综合整治措施的研究[D]. 南京:南京理工大学, 2011:14-15 Zhou H F. The study of DMF pollution monitoring and assessment and comprehensive renovation of synthetic leather industries of some region in Zhejiang[D]. Nanjing:Nanjing University of Science and Technology, 2011:14-15(in Chinese)

曾芳, 蔡泽鹏, 梁鹤山, 等. 环境空气中N,N-二甲基甲酰胺和N,N-二甲基乙酰胺测定方法研究[J]. 科学技术创新, 2018(31):8-9

United States Environmental Protection Agency. TRI-listed chemicals.. https://www.epa.gov/toxics-release-inventory-tri-program/tri-listed-chemicals

朱晓晶, 于洋, 竹涛, 等. Copeland法与证据权重法在污染物危害性排序上的对比研究[J]. 生态毒理学报, 2019, 14(3):214-225Zhu X J, Yu Y, Zhu T, et al. A comparative study of Copeland method and weight-of-evidence method application on hazard ranking of pollutants[J].Asian Journal of Ecotoxicology, 2019, 14(3):214-225(in Chinese)

丁禄彬. 含DMF废水的回收利用及处理研究[D]. 青岛:青岛科技大学, 2009:4-6 Ding L B. Resource recovery and treatment on wastewater contained DMF[D]. Qingdao:Qingdao University of Science and Technology, 2009:4-6(in Chinese)

周磊. 环境空气DMF暴露疾病的发病对照研究[D]. 杭州:浙江大学, 2012:5-7 Zhou L. Controlled study of disease incidence to the ambient air DMF exposure[D]. Hangzhou:Zhejiang University, 2012:5-7(in Chinese)

European Commission. Commission Directive 2009/161/EU of 17 December 2009 establishing a third list of indicative occupational exposure limit values in implementation of Council Directive 98/24/EC and amending Commission Directive 2000/39/EC (Text with EEA relevance) Commission Directive 2009/161/EU of 17 December 2009 establishing a third list of indicative occupational exposure limit values in implementation of Council Directive 98/24/EC and amending Commission Directive 2000/39/EC.. https://eur-lex.europa.eu/legal-content/EN/TXT/?qid=1572403350832&uri=CELEX:32009L0161

The European Parliament and the Council of the European Union. Regulation (EC) No 1223/2009 of the European Parliament and of the Council of 30 November 2009 on cosmetic products (Text with EEA relevance).. https://eur-lex.europa.eu/legal-content/EN/TXT/?qid=1572402022077&uri=CELEX:32009R1223

Government of Canada. List of ingredients that are prohibited for use in cosmetic products.. https://www.canada.ca/en/health-canada/services/consumer-product-safety/cosmetics/cosmetic-ingredient-hotlist-prohibited-restricted-ingredients/hotlist.html

中华人民共和国环境保护部, 中华人民共和国国家质量监督检验检疫总局. GB 21902-2008合成革与人造革工业污染物排放标准[S]. 北京:中国标准出版社, 2008

中华人民共和国环境保护部, 中华人民共和国国家质量监督检验检疫总局. GB 31571-2015石油化学工业污染物排放标准[S]. 北京:中国标准出版社, 2015

中华人民共和国环境保护部. HJ 449-2008清洁生产标准合成革工业[S]. 北京:中国标准出版社, 2008

中华人民共和国卫生部. GBZ 2.1-2007工作场所有害因素职业接触限值第1部分:化学有害因素[S]. 北京:中国标准出版社, 2007

中华人民共和国国家食品药监督管理总局. 化妆品安全技术规范(2015年版). (2010-04-06). http://samr.cfda.gov.cn/WS01/CL1870/140161.html

中华人民共和国国家质量监督检验检疫总局, 中国国家标准化管理委员会. GB/T29292-2012鞋类鞋类和鞋类部件中存在的限量物质[S]. 北京:中国标准出版社, 2012

中华人民共和国工业和信息化部. QB/T4342-2012服装用聚氨酯合成革安全要求[S]. 北京:中国标准出版社, 2012

中华人民共和国国家质量监督检验检疫总局, 中国国家标准化管理委员会. GB/T 35611-2017绿色产品评价纺织产品[S]. 北京:中国标准出版社, 2017

中华人民共和国国务院. 国务院关于进一步加强淘汰落后产能工作的通知. (2010-04-06). http://www.gov.cn/zhengce/content/2010-04/06/content_3060.htm

赵媛媛, 申香英, 郭春花, 等. 以技术改造促进产业升级纺织业淘汰落后步履坚实[J]. 纺织服装周刊, 2010(16):17-21

钱伯章. 环保型干法腈纶纺丝新技术[J]. 合成纤维, 2013, 42(9):6

王永军. 环保型干法腈纶纺丝新技术"梦想成真"[J]. 中国石化, 2014(4):62-63