摘要/Abstract

以PhSO₂SCH₂F为一氟甲硫基化试剂, 室温下实现了硫酚/硫醇的一氟甲硫基化反应, 高收率地合成了一系列一氟甲基二硫化物. 该方法具有反应时间短、条件温和、操作简单以及无需外加添加剂等特点, 为高效制备一氟甲基二硫化物提供了一条简便的途径.
关键词: 一氟甲硫基, 二硫化物, PhSO₂SCH₂F, 硫酚
The monofluoromethylthiolation reaction of thiophenols/mercaptans was developed at room temperature using PhSO₂SCH₂F as monofluoromethylthiolation reagent, and a series of monofluoromethyl disulfides were synthesized in good yields. This method features short reaction time, mild conditions, simple operation and no additives. It provides a simple and convenient way for the efficient preparation of monofluoromethyl disulfides.
Key words: monofluoromethylthio, disulfide, PhSO₂SCH₂F, thiophenol


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