摘要/Abstract

芳甲基叠氮化合物(ArCH2N3)可以为有机反应提供氮源,是一种性质稳定、合成简单的试剂,在有机合成化学领域被广泛应用.综述了最近五年来芳甲基叠氮化合物与烯烃在有机合成反应中的最新研究进展.分别叙述了芳甲基叠氮化合物在有机反应中与烯烃及其衍生物的底物适应范围和反应机理,为今后芳甲基叠氮化合物与烯烃类化合物的反应在有机合成中的应用提供参考.
关键词: 芳甲基叠氮化合物, 烯烃, 反应机理
Arylmethyl azides (ArCH2N3) as one of the significant nitrogen sources with stable properties, simple synthesis, have been widely used in a wide range of organic synthesis reactions. The recent progress (2014~2018) on reactions of arylmethyl azides with alkenes is summarized. In addition, the organic reactions of arylmethyl azides with types of alkenes are described respectively, with their scope of substrates and reaction mechanism. It is hoped that this review can be referred to the future application in organic synthesis of arylmethyl azides with alkenes.
Key words: arylmethyl azides, alkenes, reaction mechanism
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