陈娇玉¹， 孟冠华^1,2*， 魏 旺¹， 刘宝河¹， 丁素云¹， 何佳睿¹

1. 安徽工业大学环境工程系，安徽 马鞍山 2430002. 教育部生物膜法水质净化及利用技术工程研究中心，安徽 马鞍山 243000

收稿日期:2019-03-11修回日期:2019-06-27出版日期:2020-02-22发布日期:2020-02-19
通讯作者:陈娇玉

基金资助:安徽高校自然科学研究重点项目;2017年度高校优秀骨干青年人才国内外访学研修项目

Performance and mechanism of ozonation of bisphenol A

Jiaoyu CHEN¹, Guanhua MENG ^1,2*, Wang WEI¹, Baohe LIU¹, Suyun DING¹, Jiarui HE¹

1. School of Energy and Environment, Anhui University of Technology, Ma'anshan, Anhui 243000, China2. Ministry of Education Biofilm Process Water Purification and Utilization Technology Engineering Research Center, Ma'anshan, Anhui 243000, China

Received:2019-03-11Revised:2019-06-27Online:2020-02-22Published:2020-02-19

摘要/Abstract

摘要： 采用臭氧氧化法在动态条件下降解双酚A，考察了臭氧浓度、水样进水流速、pH、双酚A初始浓度及温度对氧化降解双酚A效果的影响，探究了臭氧氧化双酚A的反应机理。结果表明，臭氧对溶于水中的双酚A具有良好的去除效果，在反应条件(臭氧浓度11.04 mg/L、水样进水流速2 mL/min、原水pH=6.83、双酚A初始浓度10 mg/L、温度40℃)下，去除率达86.12%。增加臭氧浓度或适当升高温度可增加臭氧氧化双酚A去除率。pH和进水流速的提高会降低双酚A去除率。偏酸性条件下，臭氧降解双酚A的效果更好。臭氧氧化双酚A反应活化能较低，属于快速反应。臭氧浓度不变，增加双酚A初始浓度会使其去除率减小。臭氧氧化双酚A以臭氧直接氧化为主，同时也存在羟基自由基间接氧化。

引用本文

陈娇玉 孟冠华 魏旺 刘宝河 丁素云 何佳睿. 臭氧氧化双酚A的性能及机理[J]. 过程工程学报, 2020, 20(2): 230-236.
Jiaoyu CHEN Guanhua MENG Wang WEI Baohe LIU Suyun DING Jiarui HE. Performance and mechanism of ozonation of bisphenol A[J]. Chin. J. Process Eng., 2020, 20(2): 230-236.

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参考文献

[1]Cydzik-Kwiatkowska A, Bernat K, Zielińska, Magdalena, et al.Aerobic granular sludge for bisphenol A (BPA) removal from wastewater[J]. International Biodeterioration & Biodegradation, 2017, 122:1-11. [2]陈云峰, 杨志宝, 柳延峰, 赵泽军, 张桂华.双酚的生产及市场情况分析[J].化学工业, 2018, 36(03):42-47 [3]Toner F, Allan G, Beyer D, et al.In vitro percutaneous absorption and metabolism of bisphenol A (BPA) through fresh human skin[J]. Toxicology in Vitro, 2018, 47:14 -155. [4]Huang Y Q, Wong C K C, Zheng J S, et al.Bisphenol A (BPA) in China: A review of sources, environmental levels, and potential human health impacts[J]. Environment International, 2012, 42:0-99. [5]Desai M, Ferrini M G, Han G, et al.In vivo maternal and in vitro BPA exposure effects on hypothalamic neurogenesis and appetite regulators[J]. Environmental Research, 2018, 164:45-52. [6]Elmetwally M A, Halawa A A, Lenis Y Y, et al.Effects of BPA on of apoptotic genes and migration of ovine trophectoderm (oTr1) cells during the peri-implantation period of pregnancy[J]. Reproductive Toxicology, 2019, 83:73–79. [7]Bhatnagar A, Anastopoulos I .Adsorptive removal of bisphenol A (BPA) from aqueous solution: A review[J]. Chemosphere, 2017, 168:885-902. [8]王婧.分子印迹磁性吸附材料的制备及其吸附双酚A的效能[D].黑龙江：哈尔滨工业大学, 2017. [9]顾雍.生物降解及过硫酸盐氧化去除典型酚类有机污染物的研究[D].上海：华东理工大学, 2018. [10]Chong M N, Sharma A K, Burn S, et al.Feasibility study on the application of advanced oxidation technologies for decentralised wastewater treatment[J]. Journal of Cleaner Production, 2012, 35:230-238. [11]Mansouri L, Tizaoui C, Geissen S, et al..A comparative study on ozone, hydrogen peroxide and UV based advanced oxidation processes for efficient removal of diethyl phthalate in water[J]. Journal of Hazardous Materials, 2019, 363:401–411 [12]Liao G, Zhu D, Zheng J, et al.Efficient mineralization of bisphenol A by photocatalytic ozonation with TiO2–graphene hybrid[J]. Journal of the Taiwan Institute of Chemical Engineers, 2016, 67:300-305. [13]Keykavoos R, Mankidy R, Ma H, et al.Mineralization of bisphenol A by catalytic ozonation over alumina[J]. Separation and Purification Technology, 2013, 107:310-317. [14]Lai Y, Yang L Y .Research Progress of Water Treatment by Advanced Oxidation Technology[J]. Advanced Materials Research, 2013, 864-867:2096-2099. [15]Mansouri L, Tizaoui C, Geissen S, et al..A comparative study on ozone, hydrogen peroxide and UV based advanced oxidation processes for efficient removal of diethyl phthalate in water[J]. Journal of Hazardous Materials, 2019, 363:401–411. [16]Sharma A, Ahmad J, Flora S J S.Application of advanced oxidation processes and toxicity assessment of transformation products[J].International Journal of Molecular Sciences, 2017, 18(12):2555- [17]Garoma T, Matsumoto S.Ozonation of aqueous solution containing bisphenol A: Effect of operational parameters[J].Journal of Hazardous Materials, 2009, 167(1-3):1185-1191 [18]Ebrahiem E E, Al-Maghrabi M N, Mobarki A R.Removal of organic pollutants from industrial wastewater by applying photo-Fenton oxidation technology[J].Arabian Journal of Chemistry, 2013, 35(S2):1-13 [19]Dietrich M, Franke M, Stelter M, et al.Degradation of endocrine disruptor Bisphenol A by ultrasound-assisted electrochemical oxidation in water[J]. Ultrasonics Sonochemistry, 2017, 39:741-749. [20]张凌, 陶莹, 常志显, 李德亮.臭氧法降解水中对甲基苯磺酸的动力学研究[J].环境科学学报, 2011, 31(10):2185-2191 [21]吴光国, 谢勇冰, 邢林林.改性活性炭强化催化臭氧氧化降解草酸[J].过程工程学报, 2012, 12(4):684-689 [22]谢兆倩, 刘晨.臭氧氧化降解水中双酚的研究[J].山东化工, 2018, 47(11):190-192

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