1. 武汉科技大学钢铁冶金及资源利用省部共建教育部重点实验室,湖北 武汉 4300812. 湖北省冶金二次资源工程技术研究中心,湖北 武汉 4300813. 武汉科技大学省部共建耐火材料与冶金国家重点实验室,湖北 武汉 430081
收稿日期:
2018-12-04修回日期:
2019-02-22出版日期:
2019-08-22发布日期:
2019-08-15通讯作者:
李杨基金资助:
国家自然科学基金项目;省部共建耐火材料与冶金国家重点实验室青年基金;湖北省自然科学基金Dissolution behavior of main minerals in hydrothermal leaching process of LF refining spent slag
Huanyu HE1,2,3, Weiwei HOU1,2,3, Hongling LIU1,2,3, Yang LI1,2,3*1. Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan, Hubei 430081, China 2. Hubei Provincial Engineering Technology Research Center of Metallurgical Secondary Resources, Wuhan, Hubei 430081, China3. The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, Hubei 430081, China
Received:
2018-12-04Revised:
2019-02-22Online:
2019-08-22Published:
2019-08-15摘要/Abstract
摘要: 通过水热浸出实验分别研究了精炼废渣及合成的废渣中2种主要单一矿相12CaO?7Al2O3和2CaO?SiO2的溶解行为,并将二者进行对比分析,探究了LF精炼废渣在水热浸出过程中的溶解行为。结果表明,废渣浸出过程中浸出液的pH?12,且随浸出时间增加,电导率和Ca浓度增加,Al浓度急剧下降,Si浓度低于0.1 mg/L且保持不变;12CaO?7Al2O3浸出过程中,随时间增加,浸出液pH值稳定在约11.3,浸出液中Al浓度增加,Ca浓度略微下降。2CaO?SiO2浸出液中主要为Ca2+,Si浓度低于0.6 mg/L;废渣与单一矿相浸出过程的pH值及Al, Si浓度较接近,可以通过单一矿相的溶解行为研究精炼废渣在水热浸出过程中的溶解行为,但废渣浸出液的Al和Si浓度均低于单一矿相,表明废渣中CaO等其它组分溶解抑制了12CaO?7Al2O3和2CaO?SiO2溶解。
引用本文
何环宇 侯巍巍 刘虹灵 李杨. LF精炼废渣水热浸出过程中主要矿相的溶解行为[J]. 过程工程学报, 2019, 19(4): 735-741.
Huanyu HE Weiwei HOU Hongling LIU Yang LI. Dissolution behavior of main minerals in hydrothermal leaching process of LF refining spent slag[J]. Chin. J. Process Eng., 2019, 19(4): 735-741.
使用本文
导出引用管理器 EndNote|Ris|BibTeX
链接本文:http://www.jproeng.com/CN/10.12034/j.issn.1009-606X.218325
http://www.jproeng.com/CN/Y2019/V19/I4/735
参考文献
[1]刘航航,刘朝阳,邵伟.精炼废渣资源循环利用综述[J].炼钢, 2015, 31(2):73-78 [2]Liu H H, Liu Z Y, Shao W.The resource recycling of LF refining slag[J].Steelmaking, 2015, 31(2):73-78 [3]Wang Y , Yang S , Li J , et al. .Cyclic Use of Ladle Furnace Refining Slag for Desulfurization[J].Journal of Sustainable Metallurgy, 2016, :1-6 [4]王维,胡尚雨.冷态渣用于脱硫的研究[J].炼钢, 2011, 27(2):48-51 [5]Wang W, Hu S Y.Study on using LF cold slag for desulphurization[J].Steelmaking, 2011, 27(2):48-51 [6]Uehara N, Fujimoto K, Hanada K, et al.Fabrication of equipments treating iron and steel slags with highly-pressurized hot water and investigation of leaching of constituents from the slags[J].TETSU TO HAGANE-JOURNAL OF THE IRON AND STEEL INSTITUTE OF JAPAN, 2014, 100(8):1014-1020 [7]何环宇,王杰奇,陈振红,等.水热浸出精炼废渣物化性能研究[J].武汉科技大学学报, 2016, 39(1):7-10 [8]He H Y, Wang J Q, Chen Z H, et al.Physicochemical properties of LF refining spent slag after hydrothermal leaching[J].Journal of Wuhan University of Science and Technology, 2016, 39(1):7-10 [9] 李慧君.NH3-(NH4)2SO4-H2O体系浸出异极矿的研究[D]. 长沙:中南大学,2009:18?28. [10]Li H J.Study on the leaching of hemimorphite in the NH3-(NH4)2SO4-H2O system[D]. Changsha: Central South University, 2009: 18?28. [11]Xiaorui Zhang, Hiroyuki Matsuura and Fumitaka Tsukihashi.Dissolution mechanism of various elements into seawater for recycling of steelmaking slag[J].ISIJ International, 2012, 52(5):928-933 [12]何环宇,王杰奇,张华,等.脱硫废渣水热浸出多组分溶解行为[J].钢铁研究学报, 2018, 30(1):26-31 [13]He H Y, Wang J Q, Zhang H, et al.Dissolution of multicomponents during hydrothermal leaching of LF desulfurization slag[J].Journal of Iron and Steel Research, 2018, 30(1):26-31 [14] 万丽,欧乐明.含油酸钠氧化锌浸出液体系的溶液化学研究[J].矿产综合利用, 2015, (2):67-70 [15]Wang L, Ou L M..Solution chemistry calculation on zinc oxide lixivium containing sodium oleate[J].Multipurpose Utilization of Mineral Resources, 2015, (2):67-70 [16] 孙会兰,涂赣峰,毕诗文,等.七铝十二钙的合成及其在高碳钠铝酸钠溶液中的溶出性能[J].轻金属, 2007, (11):17-19 [17]Sun H L, Tu G F, Bi S W, et al.Synthesization of C12A7 and it’s leaching property in sodium aluminate solution with high?Na2OC[J].Light Metals, 2007, (11):17-19 [18] F. Engstr?m, D. Adolfsson, C. Samuelsson.A study of the solubility of pure slag minerals[J].Minerals Engineering, 2013, 41:46-52 [19] 黄希祜.钢铁冶金原理,第四版[M]. 北京:冶金工业出版社,2013: 212?215. [20]Huang X H.Principles of steel metallurgy, the fourth edition[M]. Beijing: Metallurgical Industry Press, 2013: 212?215. [21]汪智勇,王敏,文寨军,等.硅酸二钙及以其为主要矿物的低钙水泥的研究进展[J].材料导报, 2016, 30(1):74-75 [22]Wang Z Y, Wang M, Wen Z J, et al.Progress on study of dicalcium silicate and low calcium cement with dicalcium silicate as a main mineral composition[J].Materials Review, 2016, 30(1):74-75 [23]张雄.介质对γ?水化的影响[J].上海建材学院学报, 1989, 2(4):323-328 [24]Zhang X.Influence of media upon the hydration of γ?C2S[J].Journal of Shanghai Institute of Building Materials, 1989, 2(4):323-328 [25]严生,蔡安兰,周际东.系统水化机理[J].硅酸盐学报, 2004, 32(4):522-523 [26]Yan S, Cai A L, Zhou J D.Hydration mechanism of C2S-C12A7-CaSO4?2H2O-H2O system[J].Journal of the Chinese Ceramic Society, 2004, 32(4):522-523 |
相关文章 1
[1] | 刘继鑫李兰杰郑诗礼王少娜杜浩谢海云. 钒渣焙烧-水热碱浸提钒[J]. , 2014, 14(5): 763-769. |
PDF全文下载地址:
http://www.jproeng.com/CN/article/downloadArticleFile.do?attachType=PDF&id=3309