形貌可控的银纳米颗粒合成及应用

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王凯^1,2，汪涵^1,2，周榆^1,3，窦翔宇^1,2，韩永生^1,2*

1. 中国科学院过程工程研究所多相复杂系统国家重点实验室，北京 100190
2. 中国科学院大学化工学院，北京 100049
3. 中国石油大学(北京)化学工程学院，北京 102249

收稿日期:2018-12-13修回日期:2019-03-05出版日期:2019-10-22发布日期:2019-10-22
通讯作者:韩永生

基金资助:国家自然科学基金资助项目 (U1302274)

Synthesis and applications of silver nanoparticles with controlled morphologies

Kai WANG^1,2, Han WANG^1,2, Yu ZHOU^1,3, Xiangyu DOU^1,2, Yongsheng HAN^1,2*

1. State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
2. School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
3. School of Chemical Engineering, China University of Petroleum, Beijing 102249, China

Received:2018-12-13Revised:2019-03-05Online:2019-10-22Published:2019-10-22

Supported by:Projects (U1302274) supported by the National Science Foundation of China

摘要/Abstract

摘要： 银纳米材料具有独特的物理性质，在光学、生物和催化等领域应用潜力巨大，是近年来材料领域的研究热点。银纳米材料的很多性能与其形貌密切相关，如枝状银纳米颗粒局部表面等离子体共振较强，不同形貌的银纳米颗粒裸露不同的晶面，导致其催化选择性不同。因此，控制合成特定形貌和结构的银纳米颗粒一直是该领域的重要研究方向。本工作综述了近年来银纳米颗粒形貌可控的合成方法，包括溶液还原法、晶种法、生物合成法、光诱导法、反应-扩散调控的动力学法和模板法等，比较了不同方法的优缺点，分析了不同合成方法的机理。重点介绍了基于反应和扩散调控的动力学方法，总结了其优点和普适性。调研了不同形貌银纳米颗粒在抑菌、局部等离子体共振和催化等领域的应用研究，分析了不同形貌银纳米颗粒的工业化应用前景，并对银纳米形貌的可控合成和应用进行了展望。

引用本文

王凯汪涵周榆窦翔宇韩永生. 形貌可控的银纳米颗粒合成及应用[J]. 过程工程学报, 2019, 19(5): 919-931.
Kai WANG Han WANG Yu ZHOU Xiangyu DOU Yongsheng HAN. Synthesis and applications of silver nanoparticles with controlled morphologies[J]. Chin. J. Process Eng., 2019, 19(5): 919-931.

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