摘要/Abstract
过渡金属催化碳-碳键活化反应是近年来金属有机化学中非常热门且富有挑战性的研究领域之一.主要综述了近年来过渡金属(Rh,Ni,Pd和Ru)催化基于氮原子导向基团化合物碳-碳键活化与重组的研究进展,并对相关反应机理进行了探讨.
关键词: C-C键活化, 还原消除, 过渡金属, 金属化
Transition-metal-catalyzed C-C bond cleavage has been considered as one of the most interesting subject and challenging area in organometallic chemistry. The recent progress of transition-metal-catalyzed (Rh, Ni, Pd and Ru) nitrogen atom chelation-assisted C-C activation and controlled transformation is reviewed, and the mechanisms of these C-C activation reactions are also discussed.
Key words: C-C bond activation, reductive elimination, transition metals, metalation
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