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金属钯催化偶氮苯与Co(NO3)2·6H2O通过C-H活化邻位硝基化反应

本站小编 Free考研考试/2022-02-14

摘要/Abstract



开发了一种通过钯催化C-H活化法将偶氮苯转化成邻硝基偶氮苯衍生物的有效合成方法,它是以廉价易得的六水合硝酸钴作为硝化源,以较高收率得到了多种o-硝基偶氮苯.
关键词: C-H活化, 偶氮苯, 硝酸钴, 硝化
An efficient protocol for conversion of azobenzenes into their ortho-nitro derivatives via palladium-catalyzed C-H bond activation has been developed. Commercially available and less expensive Co(NO3)2·6H2O was used as the nitrification reagent. Various o-nitroazobenzenes were obtained in excellent yields.
Key words: C-H activation, azobenzenes, Co(NO3)2·6H2O, nitrification


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