摘要/Abstract

吡咯烷和吡咯啉作为重要的结构单元在医药、农药、材料等领域中具有广泛应用，多年来许多关于此类结构的合成方法被广泛报道.近年来，伴随金属有机化学的快速发展，金属催化不饱和烃的官能化反应具有高效性和多样性等优点，逐渐成为有机合成方法学的研究热点.因此通过金属催化不饱和烃的官能化反应构建吡咯烷和吡咯啉结构具有重要的意义.概述了各种金属催化的不同类型不饱和烃的官能化反应合成吡咯烷和吡咯啉类化合物的进展.
关键词: 金属催化, 不饱和烃, 官能化, 吡咯烷, 吡咯啉
Pyrrolidines and pyrrolines, as important building blocks, are widely applied in the fields of medicine, agriculture and materials. Many synthetic methods for the preparation of pyrrolidines and pyrrolines have been reported over the past few years. Recently, following the rapid development of organometallic chemistry, the metal-catalyzed functionalization of unsaturated hydrocarbons has gradually become the research focus of organic synthesis methodology, due to the high efficiency and diversity of functionalization. Therefore the constructions of pyrrolidines and pyrrolines using metal-catalyzed unsaturated hydrocarbon functionalization are important and very useful. The development of metal-catalyzed functionalizations of different types of unsaturated hydrocarbons for the synthesis of pyrrolidines and pyrrolines is summarized.
Key words: metal-catalyzed, unsaturated hydrocarbon, functionalization, pyrrolidine, pyrroline


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