热处理温度对磷渣-煤矸石微晶玻璃结构和性能的影响

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陈伟，管艳梅*，刘开伟，胡普华，孙道胜

安徽建筑大学材料与化学工程学院，安徽省先进建筑材料重点实验室，安徽合肥 230022

收稿日期:2018-10-11修回日期:2019-02-16出版日期:2019-04-22发布日期:2019-04-18
通讯作者:管艳梅

基金资助:煤矸石-磷渣低温制备CAS系微晶玻璃

The effects of heat treatment temperature on performance and structure of phosphorus slag-coal gangue glass-ceramics

Wei CHEN, Yanmei GUAN*, Kaiwei LIU, Puhua HU, Daosheng SUN

Anhui Key Laboratory of Advanced Building Materials, School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei, Anhui 230022, China

Received:2018-10-11Revised:2019-02-16Online:2019-04-22Published:2019-04-18

Supported by:Preparation of CaO-Al2O3-SiO2 Glass-Ceramics from Coal Gangue and Phosphor Slag via Low-Temperature Sintering

摘要/Abstract

摘要： 以磷渣和煤矸石为原料，采用一步烧结法制备了性能优良的CaO?Al2O3?SiO2(CAS)系微晶玻璃，用差示扫描量热法(DSC)，X射线衍射(XRD)和扫描电子显微镜(SEM)等对其进行分析和表征，研究了热处理温度对微晶玻璃晶相组成、微观结构和宏观性能的影响规律。结果表明，固废利用率达100%，微晶玻璃性能良好；以磷渣和煤矸石为原料在1250℃下熔融2 h、于850℃热处理保温2 h可制备主晶相为假硅灰石Ca3(Si3O9)的微晶玻璃，其抗折强度、显微硬度和体积密度分别为74.4 MPa，566.9 HV和2.75 g/cm3。随热处理温度升高，微晶玻璃主晶相由Ca3(Si3O9)相转变为硅灰石CaSiO3相，晶体形态由球状向针状、短柱状改变，对提高微晶玻璃抗折性能有利，而显微硬度和体积密度均先增加后降低。

引用本文

陈伟管艳梅刘开伟胡普华孙道胜. 热处理温度对磷渣-煤矸石微晶玻璃结构和性能的影响[J]. 过程工程学报, 2019, 19(2): 370-376.
Wei CHEN Yanmei GUAN Kaiwei LIU Puhua HU Daosheng SUN. The effects of heat treatment temperature on performance and structure of phosphorus slag-coal gangue glass-ceramics[J]. Chin. J. Process Eng., 2019, 19(2): 370-376.

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参考文献

[1] 方一航, 王焕平, 李志刚,等. Bi2O3助熔剂对CaO-B2O3-SiO2/Al2O3玻璃-陶瓷复合材料性能的影响[J]. 复合材料学报, 2014, 31(6):1509-1515.
Fang Yihang, Wang Huanping, Li Zhigang, et al. Effect of Bi2O3 flux on properties of CaO-B2O3-SiO2/Al2O3 glass-ceramic composites[J]. Acta Materiae Compositae Sinica, 2014, 31(6):1509-1515.
[2] Saadaldin S A, Rizkalla A S. Synthesis and characterization of wollastonite glass–ceramics for dental implant applications[J]. Dental Materials, 2014, 30:364-371.
[3] Toya T, Kameshima Y, Yasumori A, et al. Preparation and properties of glass-ceramics from wastes (Kira) of silica sand and kaolin clay refining[J]. Journal of the European Ceramic Society, 2004, 24:2367-2372.．
[4] 杜瑞材, 倪似愚, 常江,等. 含Zn生物玻璃、玻璃陶瓷与聚酯复合骨组织工程支架的制备及性能[J]. 复合材料学报, 2008(6):123-129.
Du Ruicai, Ni Xiangyu, Chang Jiang, et al. Preparation and properties of Zn-containing bioglass, glass-ceramic and polyester composite bone tissue engineering scaffolds[J]. Acta Materiae Compositae Sinica, 2008(6):123-129.
[5] WOLFRAM H, GEORGE B. Glass-Ceramic Technology [M]. The American Ceramic Society, 2002:1–4.
[6] 史培阳, 张影, 张大勇, 等. 矿渣微晶玻璃的析晶行为与性能[J].中国有色金属学报, 2007, 17(2):341–347.
SHI Peiyang, ZHANG Yi, ZHANG Dayong, et al. Chin J NonferrousMetals, 2007, 17(2):341–347.
[7] 程金树, 李宏, 汤李缨, 等. 微晶玻璃[M]. 北京: 化学工业出版社,2006:1–6.
Cheng Jinshu, Li Hong, Tang Lizhen, et al. Glass-ceramics [M]. Beijing: Chemical Industry Press, 2006:1–6.
[8] 尚志标, 黄小凤, 马丽萍,等. 粉煤灰和自然冷却黄磷炉渣协同制备微晶玻璃[J]. 硅酸盐通报, 2017, 36(2):533-538.
Shang Zhibiao, Huang Xiaofeng, Ma Liping, et al. Synergistic preparation of glass-ceramics from fly ash and naturally cooled yellow phosphorus furnace slag [J]. Bulletin of Silicate, 2017, 36(2): 533-538.
[9] Soon-Do, Yoon, Jong-Un, et al. Characterization of Wollastonite Glass-ceramics Made from Waste Glass and Coal Fly Ash[J]. Journal of Materials Science & Technology, 2013, 29(2):149-153.
[10] 杨淑敏, 张伟, 戴晔. 利用新疆高炉渣制备微晶玻璃的研究[J]. 硅酸盐通报, 2014, 33(1):48-53.
Yang Shumin, Zhang Wei, Dai Wei. Study on Preparation of Glass-ceramics from Xinjiang Blast Furnace Slag[J]. Bulletin of Silicate, 2014, 33(1): 48-53.
[11] 岳钦艳, 张升晓, 于慧,等. TiO2加入量对高炉渣微晶玻璃析晶的影响[J]. 过程工程学报, 2007, 7(2):327-331.
Yue Qinyan, Zhang Shengxiao, Yu Hui, et al. Effect of TiO2 Addition on Crystallization of Blast Furnace Slag Glass-Ceramics[J]. Chinese Journal of Process Engineering, 2007, 7(2):327-331.
[12] 史培阳, 姜茂发, 刘承军,等. 热处理对硼泥微晶玻璃微观结构的影响[J]. 过程工程学报, 2005, 5(2):175-178.
Shi Peiyang, Jiang Maofa, Liu Chengjun, et al. Effect of heat treatment on microstructure of boron mud glass-ceramics[J]. Chinese Journal of Process Engineering, 2005, 5(2): 175-178.
[13] Gomes V, Borba C D G D, Riella H G. Production and characterization of glass ceramics from steelwork slag[J]. Journal of Materials Science, 2002,12:2581-2585.
[14] 中国国家建材工业局标准化研究所.C/T 872-2000[S].北京：机械科学研究院标准出版中心,2001.
Institute of Standardization, China National Building Material Industry Bureau. C/T 872-2000[S]. Beijing: Standard Publishing Center of Mechanical Science Research Institute ,2001.
[15] Kissinger H E. Variation of Peak Temperature with Heating Rate in Differential Thermal Analysis[J]. Journal of Research of the National Bureau of Standards, 1956:217-221.
[16] Kissinger H E. Reaction Kinetics in Differential Thermal Analysis[J]. Analytical Chemistry, 1957, 29(11):1702-1706.
[17] Avrami M. Kinetics of Phase Change．I General theory［J］．The Journal of Chemical Physics，1939，7:1103-1112．
[18] Johnson W A. Reaction Kinetics in Processes of Nucleation and Growth[J]. Am.inst.min.metal.petro.eng, 1939, 135(8): 396-415．
[19] 姚树玉, 姚玉随, 韩野,等. CaO-Al2O3-SiO2系粉煤灰微晶玻璃的析晶动力学及电子探针分析[J]. 硅酸盐学报, 2012, 40(1):170-174.
YAO Shu-yu, YAO Yu-sui, HAN Ye, et al. Crystallization kinetics and electron probe analysis of CaO-Al2O3-SiO2 fly ash glass-ceramics[J]. Journal of The Chinese Ceramic Society, 2012, 40(1): 170-174 .
[20] 李保庆, 郭艳平, 党海峰,等. 晶化温度对钨尾矿微晶玻璃析晶性能的影响[J]. 中国陶瓷, 2017(11):63-68.
Bao Qing, Guo Yanping, Dang Haifeng, et al. Effect of Crystallization Temperature on Crystallization Properties of Tungsten Tailings Glass-Ceramics[J]. China Ceramics, 2017(11): 63-68.

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