1. 合肥工业大学汽车与交通工程学院,安徽合肥 230009
2. 合肥工业大学机械工程学院,安徽合肥 230009
3. 合肥工业大学先进能源技术与装备研究院,安徽合肥 230009
4. 安徽省环境保护产业发展促进会,安徽合肥 230000
收稿日期:
2017-11-16修回日期:
2018-01-16出版日期:
2018-08-22发布日期:
2018-08-15通讯作者:
马培勇基金资助:
国家自然科学基金项目Preparation of activated carbon from sludge and sawdust with ZnCl2 as activator
Dongqiang WU1, Peiyong MA2,3*, Song HU4, Xianjun XING2,3, Xianwen ZHANG1,31. School of Automobile and Transportation Engineering, Hefei University of Technology, Hefei, Anhui 230009, China
2. School of Mechanical Engineering, Hefei University of Technology, Hefei, Anhui 230009, China
3. Institute of Advanced Energy Technology & Equipment, Hefei University of Technology, Hefei, Anhui 230009, China
4. Anhui Province Environmental Protection Industry Development Association, Hefei, Anhui 230000, China
Received:
2017-11-16Revised:
2018-01-16Online:
2018-08-22Published:
2018-08-15Contact:
Peiyong Ma 摘要/Abstract
摘要: 以城市污水厂二沉池污泥为主要原料、固体ZnCl2为活化剂,添加一定量锯末,在高温管式炉中采用化学活化法制备污泥活性炭,通过单因素实验考察了锯末添加率、盐料比、活化温度、活化时间对污泥活性炭吸附性能的影响. 结果表明,锯末添加量为20%、盐料质量比为2.0、活化温度为550℃、活化时间为15 min时,所得活性炭碘吸附性能最优,达679.25 mg/g;污泥活性炭具有发达的孔结构,其比表面积达609.68 m2/g,总孔容为0.51 cm3/g,平均孔径为3.51 nm.
引用本文
吴东强 马培勇 胡淞 邢献军 张贤文. 污泥-锯末混合ZnCl2活化制备活性炭[J]. 过程工程学报, 2018, 18(4): 792-798.
Dongqiang WU Peiyong MA Song HU Xianjun XING Xianwen ZHANG. Preparation of activated carbon from sludge and sawdust with ZnCl2 as activator[J]. Chin. J. Process Eng., 2018, 18(4): 792-798.
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参考文献
[1]. 苏铭华. 污泥质废弃物衍生燃料的研制开发[J]. 中国资源综合利用, 2009, 27(07): 14-15. [2017-08-21]. SU M H. Research and development of sludge derived fuel [J]. China Resources Comprehensive Utilization, 2009, 27 ( 7) : 14-15 ( in Chinese). [2]. 赵丽君, 张大群, 陈宝柱. 污泥处理与处置技术的进展[J]. 中国给水排水, 2001, 17( 6): 23-25. ZHAO L J, ZHANG D J, CHEN B Z. Advances in sludge treatment and disposal technology [J]. China Water and Wastewater, 2001, 17( 6): 23-25. [3]. 刘英华. 城市污水处理厂污泥制备活性炭的研究[D]. 南京理工大学, 2008. LIU Y H. Study on Preparation of activated carbon from sewage sludge from municipal wastewater treatment plant [D]. Nanjing University of Science and Technology, 2008. [4]. 夏莉. 微波热解污泥及其产物组成的分析[D]. 大连理工大学, 2008. XIA L. Analysis of microwave pyrolysis sludge and its product composition [D]. Dalian University of Technology, 2008. [5]. MOHAMMED R, IMITRI M, OUCHRA B, et al. In-vessel treatment of urban primary sludge by aerobic composting [J]. Bioresource Technology, 2010, 101( 15) : 5988-5995. [6]. 任爱玲,王启山,贺君. 城市污水处理厂污泥制活性炭的研究[J]. 环境科学, 2004,5( 增刊 1): 48-51. REN A L, WANG Q S, HE J. Study on the activated carbon produced with sewage sludge [J]. Environmental Science, 2004, 5 (suppl 1 ) : 48-51. [7]. 李依丽,王姚,李利平,等. 污泥活性炭的制备及其性能的优化[J]. 北京工业大学学报, 2013, 39 (03): 452-458. [2017-08-21]. LI Y L, WANG Y, LI L P, et al. Preparation of activated carbon from sewage sludge and optimization of its performance [J]. Journal of Beijing University of Technology, 2013, 39 (03): 452-458. [2017-08-21]. [8]. 李依丽, 李利平, 尹晶, 等. 污泥基活性炭的两步热解优化制备及其性能表征[J]. 北京工业大学学报,2013, 39 (12): 1887-1890. [2017-08-21]. LI Y L, LI L P, YIN J, et al. Preparation and characterization of activated carbon from sewage sludge by two steps pyrolysis [J]. Journal of Beijing University of Technology, 2013, 39 (12): 1887-1890. [2017-08-21]. [9]. LI Y L, LI Y L, LI L P, et al. Preparation and analysis of activated carbon from sewage sludge and corn stalk[J]. Advanced Powder Technology, 2016, 27 (2): 684-691. [10]. 李道静,封莉,张立秋. 玉米芯掺杂对污泥基活性炭性能的影响[J]. 环境工程学报, 2012, 6(03): 1010-1014. [2017-08-21]. LI D J, FENG L, ZHANG L Q, Effect of corncob blending on properties of sludge based activated carbon [J]. Journal of Environmental Engineering, 2012, 6(03): 1010-1014. [2017-08-21]. [11]. RIO S, COQ L L, FAUR C, et al. Preparation of Adsorbents from Sewage Sludge by Steam 7‘Activation for Industrial Emission Treatment[J]. Process Safety & Environmental Protection, 2014, 84(4):258-264. [12]. TSAI W T, CHANG C Y, LEE S L. A low cost adsorbent from agricultural waste corn cob by zinc chloride activation[J]. Bioresource Technology, 1998, 64 (3): 211-217. [13]. TSAI W T, CHANG C Y, LEE S L. Preparation and characterization of activated carbons from corn cob[J]. Carbon, 1997, 35(8):1198–1200. [14]. 马培勇,武晋州,张贤文,等. K2CO3-锯末干混合制备成型活性炭[J/OL]. 过程工程学报, 1-6. (2017-07-12) [2017-08-25]. MA P Y, WU J Z, ZHANG X W, et al, Preparation of formed activated carbon from K2CO3- sawdust dry mixing [J/OL]. Journal of process engineering, 1-6. (2017-07-12) [2017-08-25]. [15]. 尹炳奎. 污泥活性炭吸附剂材料的制备及其在废水处理中的应用[D].上海交通大学,2007. YIN B K. Preparation of activated carbon adsorbent for sludge and its application in wastewater treatment [D]. Shanghai Jiao Tong University, 2007. [16]. 苑守瑞, 朱义年, 梁美娜, 等. 氯化锌活化法制备柚子皮活性炭[J]. 环境科学与技术, 2010, 33(s1): 22-25. YAN S R, ZHU Y N, LIANG M N, et al. Preparation of activated carbon from Shaddock Peel by zinc chloride activation [J]. environmental science and technology, 2010, 33(S1): 22-25 [17]. MOHANTY K, DAS D. BISWAS M N. Preparation and characterization of activated carbons from Sterculia, alata, nutshell by chemical activation with zinc chloride to remove phenol from wastewater[J]. Adsorption-journal of the International Adsorption Society, 2006, 12(2): 119-132. [18]. 翟云波. 基于化学活化法的污泥衍生吸附剂的制备及应用基础理论研究[D]. 湖南大学, 2005. ZHAI Y B. Study on Preparation and application of sludge derived adsorbent based on chemical activation method [D]. Hunan University, 2005. [19]. OZDEMIR I, SAHIN M, ORHAN R, et al. Preparation and characterization of activated carbon from grape stalk by zinc chloride activation[J]. Fuel Processing Technology, 2014, 125(9): 200-206. [20]. 赵晶晶. 污泥活性炭的制备及其应用研究[D]. 华南理工大学, 2013. ZHAO J J. Preparation and application of activated sludge from activated sludge [D]. South China University of Technology, 2013 [21]. LIU T, WIE D, ZHANG G, et al. A comparison of flocculent and granular structure of sludge on the influence of activated carbon preparation, characterization and application [J]. Rsc Advances, 2016, 6 (90): 45-52. [22]. LI Y, LI Y, LI L, et al. Preparation and analysis of activated carbon from sewage sludge and corn stalk[J]. Advanced Powder Technology, 2016, 27(2): 684-691. [23]. 张会平, 叶李艺, 杨立春. 氯化锌活化法制备木质活性炭研究[C]// 全国活性炭学术研讨会. 2004:42-45. ZHANG H P, YE L Y, YANG L C. Preparation of woody activated carbon by zinc chloride activation method [C]// Symposium on activated carbon in China. 2004:42-45. [24]. 陈金妹, 谈萍, 王建永. 气体吸附法表征多孔材料的比表面积及孔结构[J]. 粉末冶金工业, 2011, 21(2):45-49. CHEN J M, TAN P, WANG Y J. Specific surface area and pore structure of porous materials characterized by gas adsorption method [J]. powder metallurgy industry, 2011, 21 (2): 45-49. [25]. 孙媛媛. 芦竹活性炭的制备、表征及吸附性能研究[D]. 山东大学, 2014. SUN Y Y, Gian treed activated carbon preparation, characterization and adsorption properties of [D]. Shandong University, 2014 [26]. 邢献军, 孙宗康, 范方宇,等. 干法制备高中孔率生物质成型活性炭[J/OL]. 化工学报, 2016, 67(06): 2638-2644. (2016-04-05) [2017-08-25] XING X J, SUN Z K, FANG F Y, et al, Preparation of activated carbon from biomass with high porosity rate by dry process [J/OL]. Journal of chemical engineering, 2016, 67(06): 2638-2644. (2016-04-05) [2017-08-25] [27]. WARNOCK D D, LEHMANN J, KUYPER T W, et al. Mycorrhizal responses to biochar in soil concepts and mechanisms[J]. Plant & Soil, 2007, 300(2): 9-20. [28]. 赵兴兴, 王哲. 氧氟沙星在碳纳米管上的吸附机制研究[J]. 环境科学, 2014, 35(2): 663-668. ZHAO X X, WANG Z, Study on the adsorption mechanism of ofloxacin on carbon nanotubes [J]. environmental science, 2014, 35(2): 663-668. [29]. 郭文娟, 梁学峰, 林大松,等. 土壤重金属钝化修复剂生物炭对镉的吸附特性研究[J]. 环境科学, 2013, 34(9): 3716-3721. GUO W J, LIANG X F, LIN D S, et al. Heavy metal adsorption characteristics of soil remediation [J]. environmental science, biological carbon agent on CD, 2013, 34(9): 3716-3721. [30]. YANG H, XU R, XUE X, et al. Hybrid surfactant-templated mesoporous silica formed in ethanol and its application for heavy metal removal[J]. Journal of Hazardous Materials, 2008, 152(2): 690-698. |
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