1. 上海交通大学化学工程系，上海 200240
2. 上海电化学能源器件工程技术研究中心，上海 200240
收稿日期:2017-11-29修回日期:2018-01-19出版日期:2018-08-22发布日期:2018-08-15通讯作者:廖小珍基金资助:国家自然科学基金面上项目;上海市自然科学基金High yield synthesis process and performance of prussian blue cathode materials for sodium ion batteries
Liqi SUN1,2, Xiaomin YAN1,2, Wan TANG1,2, Yushi HE1,2, Zifeng MA1,2, Xiaozhen LIAO1,2*1. School of Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China
2. Shanghai Electrochemical Energy Devices Research Center, Shanghai 200240, China
Received:2017-11-29Revised:2018-01-19Online:2018-08-22Published:2018-08-15摘要/Abstract
摘要： 用高氯酸盐前躯体制备普鲁士蓝(PB)材料，考察了合成过程中前驱体成分、溶液温度、钠盐添加量及杂质含量对材料性能的影响. 结果表明，氯化亚铁作铁源时，不清洗的普鲁士蓝产物中含NaCl杂质，电化学性能明显低于经多次清洗的产物；高氯酸亚铁作铁源时，不清洗直接收集的普鲁士蓝产物初始放电容量略低于清洗产物，但长期循环稳定性更好，免清洗工艺可明显提高普鲁士蓝材料的收率，少量高氯酸钠杂质存在提高了材料的循环性能.
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孙李琪 严小敏 唐婉 何雨石 马紫峰 廖小珍. 普鲁士蓝钠离子电池正极材料高收率合成过程及性能[J]. 过程工程学报, 2018, 18(4): 809-814.
Liqi SUN Xiaomin YAN Wan TANG Yushi HE Zifeng MA Xiaozhen LIAO. High yield synthesis process and performance of prussian blue cathode materials for sodium ion batteries[J]. Chin. J. Process Eng., 2018, 18(4): 809-814.
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