摘要/Abstract

以溴代芳烃和烯丙基乙酸酯为反应原料, 发展了一种铜催化高效构建碳碳键的交叉偶联方法. 该方法通过“一锅法”策略, 有效避免了预制金属有机试剂的使用, 在较温和条件下即可实现烯丙基类化合物的高区域选择性制备.
关键词: 铜催化, 烯丙基化, 区域选择性
A practical method for the Cu-catalyzed coupling of aryl (or alkyl) halides with allylic acetates was described. This procedure effectively avoids the use of preformed Grignard reagent and affords allyl products with high to excellent regio- selectivity under relatively mild condition.
Key words: Keywords copper-catalyzed, allylation, regioselectivity


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