摘要/Abstract
过渡金属催化的不对称氧化反应，作为不对称合成的重要研究内容之一，为手性天然产物和药物的合成提供了实用便捷途径，因此其方法研究备受人们关注.重点介绍了近年来过渡金属催化的烯烃不对称氧化官能团化反应、C—H键不对称氧化反应、不对称BV氧化反应和硫醚不对称氧化反应等研究进展，并展望其未来发展趋势.
关键词: 过渡金属催化, 不对称氧化, 对映选择性, 烯烃, 碳-氢活化
Transition metal-catalyzed asymmetric oxidation, as one of important research targets of chiral synthesis, provides a direct, practical route for the synthesis of various chiral bioactive products and drugs, and has received much attention. The recent progress of the methods of transition metal-catalyzed asymmetric oxidation, especially, asymmetric oxidative functionalization of olefins, C-H bond asymmetric oxidation reaction, asymmetric BV oxidation and sulfide asymmetric oxidation is elaborated. Outlook of those issuesis is also discussed.
Key words: transition metal catalysis, asymmetric oxidation, enantioselectivity, olefin, C-H activation
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