摘要/Abstract

开发了一种新型高效的钯催化的三氟硼酸钾盐与氧杂降冰片烯的不对称开环反应的方法.在温和的条件下，可得到相应的顺-2-芳基-1，2-二氢萘-1-醇产物，其产率良好，目标产物对映体选择性较高.
关键词: 氧杂降冰片烯, 三氟钾硼酸盐, 不对称开环反应
A new, versatile and highly efficient palladium-catalyzed asymmetric ring-opening reaction of oxabenzonor-bornadienes with a wide range of potassium trifluoroborate salts was developed. The corresponding cis-2-aryl-1,2-dihydronaphthalen-1-ol products were obtained in good yields with moderate to good enantioselectivities under mild conditions.
Key words: oxabenzonorbornadiene, trifluoroborate salt, asymmetric ring-opening reaction


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