摘要/Abstract

以二芳基烯丙醇与溴乙腈为原料，开发了一种可见光诱导的合成δ-酮腈的方法.控制实验的结果表明，该反应可能是通过自由基机理进行的，溴乙腈作为氰甲基自由基源参与到反应中.
关键词: 可见光诱导, 二芳基烯丙醇, 自由基
A photocatalyzed method for the synthesis of δ-ketonitriles from the reaction of diaryl allyl alcohols with bromoacetonitrile is developed. The result of control experiments indicates that the reaction might proceed via a free radical mechanism and bromoacetonitrile was the source of cyanomethyl radical.
Key words: photocatalyzed, diaryl allyl alcohol, radical


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