摘要/Abstract
近年来在光照条件下无过渡金属参与的偶联反应受到了广泛的关注，这些反应为C-N/S/P等键的构建提供了重要的方法，也在医药、农业或材料化工等领域得到了广泛的应用.重点介绍了近五年来在无过渡金属参与下由有机光氧化还原催化剂或光敏剂诱导构建C-N/S/P等键的光氧化还原反应.
关键词: 光化学, 自由基反应, 无过渡金属参与, 交叉偶联, 绿色化学
Tremendous advance has been achieved for the transition-metal free coupling reactions induced by light these years, providing important strategies for the construction of C-N/S/P bonds, which was used frequently in the preparation of pharmaceutical drugs, agricultural products or materials and so on. In this review, the recent advance for the photo-induced coupling reactions for the construction of C-N/S/P bonds under transition-metal free conditions is reviewed.
Key words: photochemistry, radical reactions, transition-metal-free, cross-coupling, green chemistry
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