摘要/Abstract
亚磺酸钠(RSO2Na)性质稳定、合成简单、价格低廉,在有机合成化学领域被广泛应用.综述了最近五年来亚磺酸钠在合成含硫化合物反应中的最新研究进展.分别叙述了其在有机反应中构建S-C键、S-杂键(S-S键、S-N键以及S-P键)的底物适应范围和反应机理,为今后亚磺酸钠的在有机合成中的应用提供参考.
关键词: 亚磺酸钠, 含硫化合物, 反应机理
Sodium sulfinates (RSO2Na) is a kind of reagents with stable properties, simple synthesis and low price, which has been widely used in the field of organic synthesis chemistry. The recent progress (2014~2018) on synthesis of sulfur compounds by sodium sulfinates is summarized. In addition, the organic reactions on the building of S-X (S-S, S-N and S-P bond) and other types of reactions are described respectively, with their scope of substrates and reaction mechanism. It is hoped that this review can be referred to the future application in organic synthesis of sodium sulfinates.
Key words: sodium sulfiniates, sulfur compounds, reaction mechanism
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