摘要/Abstract
过渡金属催化的烯丙基取代反应是构建碳-碳键、碳-杂原子键的重要手段.由于镍价廉易得，适用性广，赢得了化学家们的广泛青睐.在过去50年里，关于镍催化的烯丙基取代反应的报道不断涌现.根据成键类型及亲核试剂的种类进行划分，总结近年来镍催化的烯丙基取代反应的进展及其在有机合成中的应用.
关键词: 烯丙基取代, 不对称催化, 镍, 过渡金属
Transition-metal catalyzed allylic substitution reaction is an important approach for constructing carbon-carbon bond and carbon-heteroatom bond. Due to its cheapness, easy access, and wide applicability in organic synthesis, nickel has attracted intense attention. Over the past 50 years, nickel-catalyzed allylic substitution reactions have been extensively studied. The progresses on nickel-catalyzed allylic substitution reactions and their applications in organic synthesis are summarized according to bond formation and nucleophilic reagent.
Key words: allylic substitution, asymmetric catalysis, nickel, transition metal
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