基本信息科学研究教育教学论文专著
基本信息

我们的研究目标是设计、合成具有潜在应用价值的分子材料，通过X-ray 单晶技术，研究其分子结构，并深入的探讨其电子结构与物理化学性质之间的内在关系。课题内容涉及到无机合成、有机合成、晶体培养等实验技术，常用的表征技术涉及X-ray 单晶衍射、X-ray粉末衍射、红外、紫外、核磁、TG-DSC、电化学、磁性以及光催化等技术。

先后共主持国家自然科学基金青年基金，国家博士后基金、黑龙江省博士后基金、哈尔滨市科技创新基金、校科研创新基金，哈尔工业大学水资源国家重点实验室开放课题等多项基金项目。

工作经历

时间工作经历

2007.8-2011.12讲师基础与交叉科学研究院

2011.12-2016.1副教授基础与交叉科学研究院

2016.1-今
副教授化工与化学学院

2013.7-2014.7 访问学者澳大利亚国立大学



教育经历
1998年-2002年, 吉林大学，精细化工专业， 本科2002年-2007年, 吉林大学，无机化学，硕博连读导师：徐吉庆 教授


近几年文章：
2019
1. Xiao Zhang*; Xinrui Zhuang; Nanxi Zhang; Xuan Luo; Chunyu Ge; Jinxue Li; Jie Wu; Qing Feng Yang; Rui Liu. A luminescent sensor based on Zn(II) coordination polymer behave selective and sensitive detection for NACs and Fe3+ ions, CrystEngComm 2019 Accepted.

2. Yixing Li; Xiao Zhang; Ping Xu; Zimin Jiang; Jianmin Sun*. The design of a novel and resistant Zn(PZDC)(ATZ) MOF catalyst for the chemical fixation of CO2 under solvent-free conditions, Inorganic Chemistry Frontiers 2019, 6, (1), 317-325.

3. Yaru Liu*; Chang Liu; Xiao Zhang*; Lan Liu; Chunyu Ge; Xinrui Zhuang; NanXi Zhang; Qingfeng Yang; Yong-Qing Huang; Zhengguo Zhang. Highly selective and sensitive detection of Fe3+, Al3+ and picric acid by a water-stable luminescent MOF, J. Solid State Chem. 2019, 272, 1-8.

4. Rong-Yan Wang; Xiao Zhang*; Jie-Hui Yu*; Ji-Qing Xu. New iodometallates(I) with in situ generated organic base derivatives as countercations (M+ =?Ag+, Cu+), J. Solid State Chem. 2019, 269, 239-245.

2018
1. Yaru Liu; Lan Liu; Xiao Zhang; Jie Wu. Four unprecedented cobalt(II) and cadmium(II) metal-organic frameworks based on a rigid tricarboxylate ligand: Synthesis, crystal structures, magnetic and fluorescence properties, J. Mol. Struct. 2018, 1156, 583-591.
2. Rong-Yan Wang; Xiao Zhang; Jie-Hui Yu; Ji-Qing Xu. New iodometallates(I) with in situ generated organic base derivatives as countercations (M+ =?Ag+, Cu+), J. Solid State Chem. 2019, 269, 239-245.
3. Jianwen Lan; Mengshuai Liu; Xingyuan Lu; Xiao Zhang; Jianmin Sun. Novel 3D Nitrogen-Rich Metal Organic Framework for Highly Efficient CO2 Adsorption and Catalytic Conversion to Cyclic Carbonates under Ambient Temperature, ACS Sustainable Chemistry & Engineering 2018, 6, (7), 8727-8735.
4. Yaru Liu; Lan Liu; Xiao Zhang; Guorui Liang; Xuebing Gong. Two zinc(II) coordination complexes based on an asymmetric multidentate ligand: syntheses, structures, selective fluorescence sensing of iron(III) ions and thermal analyses, Acta Crystallographica Section C 2018, 74, 13-20.

2017

1. Xuan Luo; Xiao Zhang; Yuanling Duan; Xiaolin Wang; Jiaming Zhao. A novel luminescent Pb(ii) - organic framework exhibiting a rapid and selective detection of trace amounts of NACs and Fe3+ with excellent recyclability, Dalton Trans. 2017, 46, (19), 6303-6311.

2. Junshuai Zhang; Tongjie Yao; Chenchen Guan; Nanxi Zhang; Xin Huang; Tieyu Cui; Jie Wu; Xiao Zhang. One-step preparation of magnetic recyclable quinary graphene hydrogels with high catalytic activity, J. Colloid Interface Sci. 2017, 491, 72-79.

3. Rong-Yan Wang; Xiao Zhang; Qi-Sheng Huo; Jie-Hui Yu; Ji-Qing Xu. New discrete iodometallates with in situ generated triimidazole derivatives as countercations (Mn+ = Ag+, Pb2+, Bi3+), RSC Adv. 2017, 7, (31), 19073-19080.

4. Yaru Liu; Zhiyan Xing; Xiao Zhang; Guorui Liang. Inorganic anion-dependent assembly of zero-, one-, two- and three-dimensional Cu(II)/Ag(I) complexes under the guidance of the HSAB theory: Synthesis, structure, and magnetic property, J. Solid State Chem. 2017, 246, 48-56.
5. Hai-Yang Guo; Xiao Zhang; Li-Na Xiao; Xiao-Bing Cui. An unprecedented antimonato-polyoxovanadate (SbPOV) based on both [small alpha]-[V14Sb8O42]4- and [small beta]-[V14Sb8O42]4- isomers, Dalton Trans. 2017, 46, (25), 8022-8026.

6. Xiangxiang Gao; Mengshuai Liu; Jianwen Lan; Lin Liang; Xiao Zhang; Jianmin Sun. Lewis Acid–Base Bifunctional Crystals with a Three-Dimensional Framework for Selective Coupling of CO2 and Epoxides under Mild and Solvent-Free Conditions, Cryst. Growth Des. 2017, 17, (1), 51-57.

7. Xiao Zhang; Xuan Luo; Yuanling Duan; Yanping Huang; Nanxi Zhang; Liyan Zhao; Jie Wu. Two new hybrid molybdenum arsenate derivative constructed from [As2Mo6O26]6- building: Synthesis, structural characterization and photocatalysis property, J. Mol. Struct. 2017, 1141, 245-251.

8. Xiao Zhang; Yuanling Duan; Nanxi Zhang; Liyan Zhao; Xuan Luo; Jie Wu; Xiaoyang Yu. Highly Selective and Sensitive Detection of Nitroaromatic Compounds and Metal Ions by Supramolecular Assemblies of 3,3’,5,5’-Azobenzenetetracarboxylic Acid and 4,4’-Bipyridine, Journal of Fluorescence 2017, 27, (1), 281-286.

9. Ting-Ting Zhang; Xiao Zhang; Ying Lu; Guo-Dong Li; Li-Na Xiao; Xiao-Bing Cui; Ji-Qing Xu. New organic-inorganic hybrid compounds based on [SiNb12V2O42]12- with high catalytic activity for styrene epoxidation, Inorganic Chemistry Frontiers 2017, 4, (8), 1397-1404.

2016

(7) S.-W. Sun*; X. Zhang*; G.-F. Wang. Synthesis of 2-arylidenebenzocycloalkanones containing N-donor heterocyclic rings. Crystallogr. Rep. 2016, 61, 1072-1076.

(8) Gao-Feng Wang*; Xiao Zhang*; Shu-Wen Sun; Hong Sun; Xia Yang; Hui Li; Chen-Zhong Yao; Shu-Gang Sun; Yu-Peng Tang; Li-Xin Meng: Syntheses, crystal structures, and characterization of two Mn(II) coordination polymers with bis(4-(1H-imidazol-1-yl)phenyl)methanone ligands. In Zeitschrift für Naturforschung B, 2016; Vol. 71; pp 869-874.

(9) Jiang-Feng Song*; Si-Zhe Li; Rui-Sha Zhou; Tuo-Ping Hu; Jia Shao; Xiao Zhang*. Two new Pb coordination polymers derived from pyrimidine-2-thiolate: Synthesis, methyl substitution-induced effect and properties. J. Mol. Struct. 2016, 1116, 62-66.

(10) Jiang-Feng Song*; Ying-Ying Jia; Jia Shao; Rui-Sha Zhou; Si-Zhe Li; Xiao Zhang*. Three new complexes based on methyl-pyrimidine-2-thione: in situ transformation, crystal structures and properties. J. Coord. Chem. 2016, 69, 3072-3083.

(11) Jiang-Feng Song; Si-Zhe Li; Rui-Sha Zhou; Jia Shao; Xiao-Min Qiu; Ying-Ying Jia; Jun Wang; Xiao Zhang. Three novel Cu6S6 cluster-based coordination compounds: synthesis, framework modulation and the sensing of small molecules and Fe3+ ions. Dalton Trans. 2016, 45, 11883-11891.

(12) Po-Han Lin; Hai-Yang Guo; Xiao Zhang*; Xiao-Bing Cui*; Qi-Sheng Huo; Ji-Qing Xu. A new compound based on polyoxoniobates and three types of copper complexes. Inorg. Chem. Commun. 2016, 73, 34-36.

(13) Jing-jing Huang; Xiao Zhang*; Qisheng Huo; Jie-hui Yu*; Ji-Qing Xu. 3,5-Bis(4?-carboxylbenzyl)oxy)benzoilate-based coordination polymers: synthesis, structural characterization, and sensing property. Inorganic Chemistry Frontiers 2016, 3, 406–416.

(14) Yang-Yang Hu; Ting-Ting Zhang; Xiao Zhang*; De-Chuan Zhao; Xiao-Bing Cui; Qi-Sheng Huo; Ji-Qing Xu. New organic-inorganic hybrid compounds constructed from polyoxometalates and transition metal mixed-organic-ligand complexes. Dalton Trans. 2016, 2562–2573.

(15) Hai-Yang Guo; Xiao Zhang; Xiao-Bing Cui; Qi-Sheng Huo; Ji-Qing Xu. Vanadoantimonates: from discrete clusters to high dimensional aggregates. CrystEngComm 2016, 18, 5130-5139.

(16) Hai-Yang Guo; Zhi-Fang Li; Xiao Zhang*; Li-Wei Fu; Yang-Yang Hu; Lan-Lan Guo; Xiao-Bing Cui; Qi-Sheng Huo; Ji-Qing Xu. New self-assembly hybrid compounds based on arsenic-vanadium clusters and transition metal mixed-organic-ligand complexes. CrystEngComm

2016, 18, 566-579.

2015

(17) De-Chuan Zhao; Yang-Yang Hu; Hong Ding; Hai-Yang Guo; Xiao-Bing Cui*; Xiao Zhang*; Qi-Sheng Huo; Ji-Qing Xu. Polyoxometalate-based organic-inorganic hybrid compounds containing transition metal mixed-organic-ligand complexes of N-containing and pyridinecarboxylate ligands. Dalton Trans. 2015, 44, 8971-8983.

(18) Xiao-Yang Yu; Xiao Zhang*; Xiao-Shu Qu; Ming-Shuo Ma; Zhi-Gang Liu; Li Jin; Yan-Yan Yang; Ya-Nan Luo*. A new 3-D Cd(II) coordination polymer with metallacalix[4]arene building blocks based on 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid. J. Coord. Chem. 2015, 68, 3580-3588.

(19) Li-Na Xiao; Xiao-Jing Song; Li-Wei Fu; Yang-Yang Hu; Hai-Yang Guo; Xiao-Bing Cui*; Ming-Jun Jia*; Xiao Zhang*; Jia-Ning Xu; Ji-Qing Xu. Two novel structures based on an organic ligand with two different coordination modes. RSC Adv. 2015, 5, 46790-46800.

(20) Gao-Feng Wang*; Xiao Zhang*; Shu-Wen Sun*; Qiu-Ping Han; Xia Yang; Hui Li; Hui-Xuan Ma; Chen-Zhong Yao; Hong Sun; Hong-Bo Dong*. Synthesis and crystal structure of a novel Mn(II) coordination polymer with 3-(4-(1H-benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one ligands. Crystallogr. Rep. 2015, 60, 1038-1043.

(21) Gao-Feng Wang*; Xiao Zhang*; Shu-Wen Sun; Chen-Zhong Yao; Zhao-Rong Liu; Yu-Chun Wang; Yuan-Zhong Liu*: Synthesis and structural characterization of a novel copper(II)/lead(II) heterometallic organic–inorganic hybrid. In Zeitschrift für Naturforschung B, 2015; Vol. 70; pp 617-623.

(22) Gao-Feng Wang*; Xiao Zhang*; Shu-Wen Sun; Hong Sun; Hui-Xuan Ma. Synthesis and structural characterization of two half-sandwich nickel(II) complexes with the scorpionate ligands. Crystallogr. Rep. 2015, 60, 1032-1037.

(23) Shu-Wen Sun*; Xiao Zhang*; Gao-Feng Wang. Synthesis and crystal structure of a copper complex with (E)-2-(4-(1H-1,2,4-triazol-1-yl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one ligand. Crystallogr. Rep. 2015, 60, 1044-1048.

(24) Yang-Yang Hu; Xiao Zhang*; De-Chuan Zhao; Hai-Yang Guo; Li-Wei Fu; Lan-Lan Guo; Xiao-Bing Cui*; Qi-Sheng Huo; Ji-Qing Xu. Tuning the structures based on polyoxometalates from 1-D to 2-D by using different secondary organic ligands. Dalton Trans. 2015, 44, 14830-14841.

(25) Xiaohui Guo; Xiao Zhang*; Liyan Zhao; Nanxi Zhang; Zhihui Yi. Synthesis and crystal structure of cadmium coordination polymer with 1,3,5-benzenetricarboxylic acid. Crystallogr. Rep. 2015, 60, 860-864.


荣誉称号
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主要任职
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科研项目

项目名称可见光催化多酸处理工业污水中的有机及金属污染物的研究

项目来源国家自然科学

开始时间2012-01-01

结束时间2014-12-01

项目经费25

担任角色负责

项目类别横向项目

项目状态完成



项目名称取代型金属氧簇的新合成途径及其结构与功能特性的研究

项目来源市科技创新专项基金

开始时间2011-04-01

结束时间2012-04-01

项目经费2.7

担任角色负责

项目类别横向项目

项目状态完成



研究领域
光催化降解污水中的污染物多金属氧酸盐的合成、结构与功能特性的研究配位聚合物的合成、结构与功能特性的研究荧光探针检测有毒有机物
主要研究方向:利用x-ray单晶衍射技术，结合多种谱学表征，分析物质的结构与组成，并深入系统的研究化合物的功能特性，如：催化、磁性荧光等

毕业就业
谷献模 2011年毕业，中科院山西煤炭化学所，助理研究员

刘 蕾 2013年毕业，国企

樊淑鸽 2013年毕业，华能大庆热电有限公司，研发工程师

黄燕萍 2014年毕业，钦州学院，教师

郭小会 2015年毕业，凯龙蓝烽新材料科技有限公司，研发工程师

段源羚 2016年毕业，德国 康斯坦茨大学，在读博士

罗旋 2007年毕业，珠海光宇电池有限公司，项目工程师


讲授课程
《配位化学》 本科生选修课
《无机化学》 本科生学位课《物理有机化学》 研究生 学位课

招生信息
暂无填写


论文期刊

论文标题Influence of the steric hindrance of organic amines on the supramolecular network based on polyoxovanadates

作者Z. H. Yi, X. Y. Yu, W. J. Xia, L. Y. Zhao, C. Yang, Q. Chen, X. L. Wang, X. Z. Xu, X. Zhang.

期刊名称Crystengcomm

期卷12, 242-24



论文标题pH-dependent assembly of a series of inorganic-organic hybrid molybdenum(v) phosphate

作者X. Zhang, Z. H. Yi, L. Y. Zhao, Q. Chen, X. L. Wang, J. Q. Xu, W. J. Xia, C. Yang

期刊名称 Crystengcomm

期卷 2010, 12,



论文标题Fluorescent metal-organic polymers of zinc and cadmium from hydrothermal in situ acylation reaction

作者X. Y. Yu, L. Ye, X.Zhang, X. B. Cui, J. P. Zhang, J. Q. Xu, Q. Hou, T. G. Wang

期刊名称 Dalton Trans.

期卷 2010, 39,



论文标题Steric hindrance-dependent rational design and synthesis of three new Keggin-based supramolecular networks

作者X. Zhang, Z. H. Yi, L. Y. Zhao, Q. Chen, X. M. Gu, J. Q. Xu, X. L. Wang, C. Yang, X. Z. Xu, W. J. Xia

期刊名称Dalton Trans

期卷2009, 9198



论文标题Formation of a 3D Porous Ferric Arsenate Containing Novel Cubane-like Fe4F4 Building Units

作者Z. H. Yi, C. Yang, W. J. Xia, X. Z. Xu, X. Zhang

期刊名称Inorg. Chem.

期卷2009, 48,