氧化铝载体改性及其应用研究进展

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孙克宁¹，马茜茜¹，侯瑞君^1*，李敏香¹，张春刚²

1. 北京理工大学化学与化工学院，北京 100081 2. 中国石油天然气股份有限公司大庆石化分公司，黑龙江大庆 163000

收稿日期:2018-09-06修回日期:2018-11-14出版日期:2019-06-22发布日期:2019-06-20
通讯作者:孙克宁

基金资助:国家自然科学基金项目;中国石油科技创新基金项目

Research progress in modification of alumina support and its application

Kening SUN¹, Xixi MA¹, Ruijun HOU^1*, Minxiang LI¹, Chungang ZHANG²

1. Beijing Institute of Technology University, School of Chemistry and Chemical Engineering, Beijing 100081, China 2. Petro China Daqing Petrochemical Company, Daqing, Heilongjiang 163000, China

Received:2018-09-06Revised:2018-11-14Online:2019-06-22Published:2019-06-20
Contact:SUN ke-ning

摘要/Abstract

摘要： 氧化铝不仅价格低廉、易获取，且具有多孔性、大比表面积、高分散性、高热稳定性等优点，常用作催化剂载体，广泛应用于工业催化领域。氧化铝的孔结构对工业催化剂性能影响很大。为优化氧化铝载体的性能，对氧化铝的扩孔和添加助剂改性已进行了大量研究。扩孔改性可降低扩散阻力并改善传质、提高活性位点的有效利用率、增强抗结焦性能，进而提高加氢催化的产率；添加助剂改性可有效抑制氧化铝载体高温烧结和相变，防止孔结构被破坏，提高催化剂的寿命。本工作介绍了制备氧化铝的方法?拟薄水铝石脱水法和溶胶?凝胶法，综述了氧化铝的扩孔方法，总结了改性氧化铝载体的最新研究进展，包括自组装法、水热处理法、扩孔剂法；阐述了氧化铝添加助剂的改性方法，包括加入稀土金属氧化物、碱(土)金属氧化物、其它金属氧化物及非金属氧化物。最后，展望了氧化铝未来的研究和发展方向。

引用本文

孙克宁马茜茜侯瑞君李敏香张春刚. 氧化铝载体改性及其应用研究进展[J]. 过程工程学报, 2019, 19(3): 465-472.
Kening SUN Xixi MA Ruijun HOU Minxiang LI Chungang ZHANG . Research progress in modification of alumina support and its application[J]. Chin. J. Process Eng., 2019, 19(3): 465-472.

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