摘要/Abstract

报道了无金属可见光诱导的苯乙酸衍生物脱羧. 在无添加剂条件下, 使用廉价的氘源成功地实现了酸的直接脱羧单氘化. 此外, 在空气存在时, 类似的催化体系能够通过脱羧氧化生成酮.
关键词: 光化学, 无金属, 脱羧, 氘代
A metal-free visible light-induced decarboxylation of phenylacetic acid derivatives has been successfully developed. Without the additives, direct decarboxylative monodeuteration of acids was successfully achieved using cheap deuterium sources. Besides, in presence of air, similar catalytic systems provided ketone products.
Key words: photochemistry, metal-free, decarboxylation, deuteration


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