摘要/Abstract
Minisci反应是指亲核性的碳自由基与缺电子含氮芳杂环间发生的自由基取代反应, 是构建新的碳-碳键的一种重要方法. 另一方面, 作为一种绿色合成的技术和手段, 有机电合成近几年来再次受到人们的关注. 介绍了近期电化学条件下Minisci反应的研究进展.
关键词: Minisci反应, 有机电合成, 光电化学, 氧化还原反应
Minisci reaction, an important method for the construction of new carbon-carbon bonds, refers to one kind of the radical substitution reactions between a nucleophilic carbon radical and an electron-deficient nitrogen-containing aromatic heterocycle. Besides, organic electrosynthesis is experiencing a renaissance as a green synthesis technology and means. This review focuses on the recent advances in Minisci reactions under electrochemical conditions.
Key words: Minisci reactions, organic electrosynthesis, photoelectrochemistry, redox reactions
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