摘要/Abstract
通过电氧化苯硫酚和胺合成了一系列次磺酰胺化合物. 该电合成反应无需金属催化剂和氧化剂, 采用简单的装置如单室电解槽, 并且使用恒电流电解, 具有底物范围广、原料简单易得、操作简便和环境友好等优点, 为结构多样的次磺酰胺的合成提供了简洁的新策略.
关键词: 次磺酰胺, 有机电合成, S—N键形成, 脱氢偶联
A series of sulfenamide compounds are synthesized by electrooxidation of thiophenols and amines. The electrosynthesis reaction does not require metal catalysts and oxidizing reagents, and uses simple devices such as single- chamber electrolyzers and constant current electrolysis. This method featured broad substrate scope, ready availability of starting materials, operational simplicity and environmental friendly, which provides a new strategy for the simple and convenient synthesis of various sulfenamide derivatives.
Key words: sulfenamides, organic electrosynthesis, S—N bond formation, dehydrogenative coupling
PDF全文下载地址:
点我下载PDF
