摘要/Abstract

环丙烯是一类最小的不饱和环状化合物, 其在有机化学中是十分重要的合成中间体, 同时在高分子聚合中也是一类独特的单体. 尽管环丙烯的研究大部分集中于有机化学领域, 近年来有关过渡金属催化的环丙烯聚合反应也逐渐引起了人们的兴趣. 综述了环丙烯聚合反应的研究进展, 主要包括加成聚合和开环复分解聚合(ROMP)两类聚合反应, 并从聚合物合成方法学的角度对于该领域的未来发展进行了展望.
关键词: 环丙烯, 过渡金属催化, 加成聚合, 开环复分解聚合
As the smallest unsaturated cyclic compounds in nature, cyclopropenes serve as important synthetic intermediates in organic chemistry as well as unique monomers in polymerization. While cyclopropenes are mostly explored in the domain of organic chemistry, the polymerization reaction of cyclopropenes has gradually attracted the attentions of chemists in recent years. The research progress of cyclopropene polymerization is reviewed, including addition polymerization and ring-opening metathesis polymerization (ROMP), and prospects for the future development of this field from the perspective of polymer synthesis methodolody.
Key words: cyclopropene, transition-metal catalysis, addition polymerization, ring-opening metathesis polymerization


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