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N-烷基胺类作为多功能砌块在氧化偶联反应中的应用

本站小编 Free考研考试/2022-02-14

摘要/Abstract



N-烷基胺的氧化官能团化是形成碳-碳键和碳-杂原子键的最直接和通用的策略之一. 近年来, N-烷基胺类作为多功能砌块在交叉脱氢偶联(CDC)反应中取得了长足发展. 基于N-烷基胺的不同角色, 总结了近年来它们在氧化偶联反应中的应用进展.
关键词: N-烷基胺, N,N-二甲基苯胺, 四氢异喹啉, 交叉脱氢偶联反应
The oxidative functionalization of N-alkylamines is one of the most direct and versatile strategies for the formation of C—C and C-heteroatom bonds. In recent years,N-alkylamines as multifunctional blocks have made great progress in cross- dehydrogenation-coupling (CDC) reactions. The recent progress in the application of N-alkylamines is summarized on the basis of different roles in oxidative coupling reactions.
Key words: N-alkylamines, N,N-dimethylamine, tetrahydroisoquinoline, cross-dehydrogenative-coupling reaction


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