摘要/Abstract

有机硒化物是一类重要的分子, 在药物、农用化学品、有机材料以及催化等领域有着广泛的应用, 在有机分子中引入硒原子在合成化学中具有重要意义. 杂环化合物是构成多种生物活性分子的重要骨架, 因此, 合成含硒杂环衍生物的研究备受关注. 分别描述了近年来快速发展的金属催化、电化学驱动、可见光驱动、有机分子催化以及其它类型的硒环化反应, 并对部分反应的适用范围和机理进行了讨论.
关键词: 有机硒化物, 杂环化合物, 硒环化, 催化
Organic selenides are a kind of important molecules, which are widely used in medicine, agricultural chemicals, organic materials and catalysis, the introduction of selenium atom into organic molecules is of great significance in the synthetic chemistry. Heterocyclic compounds are key skeletons involved in a variety of bioactive molecules, therefore, the development of new methods for the synthesis of selenium-containing heterocyclic derivatives has attracted much attentions. The recent progress in this rapidly growing area, including metal catalysis, electrochemical catalysis, visible-light catalysis, organocatalysis, and other selenocyclization types, is highlighted with an emphasis on the scope and the mechanisms of these different reactions.
Key words: organic selenide, heterocyclic compound, selenocyclization, catalysis


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