摘要/Abstract

开发了一种环境友好的可见光诱导的方法，该方法是在无光催化剂的条件下，由硝基烯烃与亚磺酸反应合成乙烯基砜.操作简单，反应条件温和，底物范围广，目标产物收率高，使得这种方法前景广阔.活性测试表明，部分目标化合物对苹果腐烂菌与柑橘炭疽病菌具有中等以上的抑制率.
关键词: 可见光, 乙烯基砜, 硝基烯烃, 亚磺酸
An eco-friendly visible light-induced approach for the synthesis of vinyl sulfones from the reaction of nitroolefins with sulfinic acid under photocatalyst free conditions was developed. Simple operation, mild reaction conditions, broad substrate scope and good yields of the desired products made this transformation have an excellent prospect. The anti-microbial activity test showed that some of the desired products had moderate inhibitory rate against V. mali and C. glecosporioides.
Key words: visible light, vinyl sulfones, nitroolefins, sulfinic acid


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