摘要/Abstract

发展了一种由烷基碘向醇转化的温和方法.该反应的发生需要三（三甲硅基）硅烷/氧气存在，同时可以通过可见光照射加速.不同类型的烷基碘化物，如一级、二级和三级烷基碘化物都能顺利发生反应，以38%~99%的收率得到相应的醇化合物.
关键词: 三(三甲硅基)硅烷, 光催化, 碳自由基, 烷基碘, 醇
A mild method for the conversion of alkyl iodides to alcohols was developed. The transformation was promoted by tris(trimethylsilyl)silane/O₂ and accelerated by photoredox catalysis under visible light irradiation conditions. Various alkyl iodides, including primary, secondary and tertiary iodides, can be smoothly converted to the corresponding alcohols in 38%~99% yields.
Key words: tris(trimethylsilyl)silane, photoredox catalysis, carbon radical, alkyl iodide, alcohol


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