摘要/Abstract

报道了钯催化下α-取代苄腈作为亲核试剂，与支链烯丙基碳酸酯的烯丙基烷基化反应，在易得的大位阻氮杂环卡宾配体存在下，以良好的收率、区域选择性及非对映选择性得到支链烯丙基烷基化产物.
关键词: 钯, 苄腈, 支链烯丙基碳酸酯, 烯丙基烷基化
Pd-catalyzed allylic alkylation reaction of α-substituted benzyl nitriles with branched allyl carbonates in the presence of bulkier N-heterocyclic carbene ligand was reported, which provided the corresponding allylated products in good yield with high regio- and diastereo-selectivity.
Key words: palladium, benzyl nitriles, branched allyl carbonates, allylic alkylation reaction


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