摘要/Abstract
以K2S2O8为氧化剂,芳基硼酸与氟仿衍生的AgCF3发生氧化偶联反应生成三氟甲基取代的芳烃及杂芳烃.该反应为构建Caryl—CF3键提供了新方法.
关键词: 氧化三氟甲基化反应, 硼酸, 氟仿, 三氟甲基银
A silver-mediated oxidative coupling reaction of arylboronic acids with fluoroform-derived AgCF3 using K2S2O8 as oxidant was developed. This reaction provides a new route to trifluoromethylated arenes.
Key words: oxidative trifluoromethylation, arylboronic acids, fluoroform, trifluoromethyl silver
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