摘要/Abstract

三氯化铝（AlCl₃）作为硬路易斯酸的典型代表，其促进的有机转化近些年来越来越受到人们的关注.总结了近10年来通过三氯化铝对含卤素、氧、氮、硫原子化合物及π键的活化完成的多种有机转化，并对所涉及的相关反应及活化机制进行了系统介绍，同时对三氯化铝新的应用领域进行了展望.
关键词: 三氯化铝, 活化作用, 活化机制, 有机催化
As a representative hard Lewis acid, aluminum trichloride (AlCl₃) has attracted more and more attention in the past decades. The reactions promoted via the activation of halogens, oxygen, nitrogen, sulfur compounds and π-bonds with AlCl₃ are systematically reviewed, and some recent progress in last ten years is updated as well. Moreover, the new application fields of AlCl₃ are prospected.
Key words: aluminum trichloride, activation, activation mechanism, organic catalysis


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