摘要/Abstract

过渡金属催化C-C键活化是有机化学一个热点和难点领域，吸引着人们广泛的关注.C-C键活化可以为很多复杂分子的合成提供简单、快速和原子经济性的方法.相比于钯、铑和铱等过渡金属催化剂，镍催化剂有很多优点，更加经济适用，也表现出独特的催化活性，备受化学家们的青睐.主要介绍了近些年镍催化C-C键断裂反应的研究进展.
关键词: 镍, C—C键活化, 过渡金属
Transition-metal catalyzed C-C bond cleavage reaction is one of the most challenge topics, and has drawn considerable attention in recent years. This process has not only emerged as a useful strategy for syntheses of complex molecular skeletons, but also satisfied atom economy. Compared to the noble transition metals catalysis such as Rh, Pd and Ir, the nickel catalysis offered a more cost effective option and exhibited unique activity or selectivity. This recent advances on the Ni-catalyzed C-C bond activations are summarized.
Key words: nickel, C-C bond activation, transition-metal


PDF全文下载地址:

点我下载PDF