摘要/Abstract

过去几十年中，碳氢官能团化反应由于其反应高效简单、原子经济性高等特点，成为近年来化学家们研究的热点之一.在此类反应中，过渡金属与氧原子之间的弱配位作用已经成为芳烃的C（sp²）-H烯基化反应的重要策略.综述了近年来过渡金属催化的具有含氧官能团（羟基、芳基醚、醛基、羰基、羧基、酰胺、磷酸和磺酸及其衍生物）的芳烃C（sp²）-H烯基化反应，并展望了其未来发展趋势.
关键词: 碳氢官能团化, 过渡金属, 弱配位, 烯基化
Over the past decade, the C(sp²)-H functionalization has emerged as a powerful methodology due to its high efficiency, simplicity, and high atomic economy. Among them, weak coordination between transition metal and oxygen atom has become an important strategy for C(sp²)-H alkenylation of arenes. In this paper, the transition metal-catalyzed C(sp²)-H alkenylation of substrates containing hydroxy, aryl ether, aldehyde, carbonyl, carboxyl, amide, phosphoric acid and sulfonic acid and their derivatives groups is reviewed, and its future development trends are prospected.
Key words: C(sp²)-H functionalization, transition metal, alkenylation, weak coordination


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