摘要/Abstract
在无金属条件下通过自由基偶联反应,实现了醚类与N-氧化物的C-2烷基化反应,反应条件温和,只需加入氧化剂二叔丁基过氧化物(DTBP)就能够以中等至高产率获得各种所需产物.
关键词: 喹啉-N-氧化物, 醚, 烷基化, 自由基偶联
The C-2 alkylation of ethers and N-oxides was achieved via free radical coupling reaction under metal-free conditions. The reaction conditions are mild, and the desired products can be obtained in medium to high yields with the addition of the oxidant di-tert-butyl peroxide (DTBP).
Key words: quinoline N-oxides, ethers, alkylation, radical cross
PDF全文下载地址:
点我下载PDF