摘要/Abstract

研究了二芳基膦氢和萘醌单酮的不对称加成反应，在Pincer钯催化剂存在下，以中等到良好的产率和对映选择性合成了相应的手性膦化合物，进一步拓宽了Pincer钯催化剂的底物应用范围.
关键词: 钯催化, 二芳基磷氢, 不对称加成
An asymmetric 1,4-addition reaction of diarylphosphines with quinone monoketals was studied. Pincer Pd complex was used as catalyst to generate a series of chiral phosphorus compounds with moderate to good enantioselectivities in high yields.
Key words: palladium catalysis, diarylphosphine, asymmetric addition


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