摘要/Abstract
发展了一种钯催化的烯烃分子内氟芳基化反应，以ArIF2作为氟源和亲电试剂来活化烯烃，实现了4-芳基-1-丁烯的氟化关环反应，以中等到良好的收率得到氟芳基化产物.这类反应为从烯基芳烃出发合成氟代四氢萘和氟代色满提供了高效方法.
关键词: 钯催化, 烯烃, 氟芳基化, 四氢萘
A novel palladium-catalyzed intramolecular fluoroarylation of alkenes has been developed, in which ArIF2 was employed as fluorine source as well as I(Ⅲ) reagent to activate olefin, to deliver the fluoroarylation products from 4-aryl- 1-olefins in moderate to good yields. The current transformation presents a convenient method to provide fluorotetralins and fluorochromanes under mild conditions from alkenes tethered arenes.
Key words: palladium-catalyzed, alkenes, fluoroarylation, tetralin
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