摘要/Abstract
过渡金属催化的C-H键官能团化策略因其高原子和步骤经济性而备受关注.亚胺因其多样性的反应活性而在构建结构新颖的含氮化合物中得以广泛应用,侧重综述了近年来亚胺参与的C-H键官能团化/环化反应的最新研究进展,并对其反应类型和相关机理予以论述.
关键词: 亚胺, 过渡金属催化, C-H键官能化, 氮杂环化合物
Transition metal-catalyzed direct C-H bond functionalization strategy has aroused wide concerns due to its high atom-economy and step-economy. Imine synthons exhibit diverse reactivities and are commonly employed to assemble nitrogen-containing complex molecules through direct C-H functionalization strategies, their reaction types and mechanisms are summarized in this paper.
Key words: imines, transition metal-catalysis, C-H bond functionalization, azaheterocycles
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