摘要/Abstract

普通的液体酸催化剂在应用过程中难免产生环境问题，全氟烷基磺酰亚胺配合物因其特殊的阴离子结构以及所具有的超酸性质而在新型催化领域表现出广泛的应用前景.介绍了全氟烷基磺酰亚胺配合物的结构与性能特点，综述了近年来全氟烷基磺酰亚胺及其配合物的制备方法，重点阐述了全氟烷基磺酰亚胺及其配合物固载化的方法及在催化反应中的最新研究进展，以期对其催化性能和应用前景有比较全面的认识.
关键词: 全氟烷基磺酰亚胺, 合成, 固载, 催化
Traditional liquid acid catalysts have environmental problems during their application. Perfluoroalkylsulfonylimide complexes show a wide application in catalysis due to their special anionic structures and super acid properties. The structures and properties of bis(perfluoroalkylsulfonyl)imide complexes are introduced. The synthesis and immobilization methods of bis(perfluoroalkylsulfonyl)imide complexes are summarized. The use of immobilized bis(perfluoroalkylsulfonyl)imide complexes in catalytic reactions is also reviewed. The development trends of perfluoroalkylsulfonylimide complexes in the catalytic application are prospected.
Key words: bis(perfluoroalkylsulfonyl)imide, synthesis, immobilization, catalysis


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