摘要/Abstract
在水相碘/三苯基膦体系中，以无嗅、易操作的芳基亚磺酸钠为硫源，合成了炔硫醚和不对称硫醚化合物.该法相比于其他文献的方法，具有操作简单、无过渡金属参与、无需使用有机溶剂和产率高等优点.
关键词: 水相反应, 芳基亚磺酸钠, 炔硫醚, 不对称二硫醚
A new approach for the synthesis of alkynyl sulfides and asymmetric disulfides with odorless, easy-to-handle sodium arylsulfiniates as the sulfur source in I2/PPh3 aqueous system has been developed. Compared with reported approaches, this protocol provides several merits including simple procedures, free of transition-metal catalysts and organic solvent, and high yields.
Key words: reaction in water, sodium arylsulfiniate, alkynyl sulfide, asymmetric disulfide
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