摘要/Abstract

合成了一种手性1，1'-联萘-2，2'-二苯膦（BINAP）功能化的多孔有机聚合物，用碳固体核磁谱（¹³C CP/MAS NMR）、磷固体核磁谱（³¹P CP/MAS NMR）、傅里叶变换红外光谱（FT-IR）、粉末X射线衍射（PXRD）、扫描电子显微镜（SEM）、透射电子显微镜（TEM）、氮气吸附和热重分析（TG）对材料进行表征，这个材料具有无定型的微孔结构.与Ru（Ⅱ）络合后，复合材料Ru/POP-BINAP可非均相催化β-酮酸酯的不对称氢化，并表现出优良的催化活性、对映选择性和循环性.
关键词: 孔有机聚合物, 非均相催化, 不对称氢化, β-酮酸酯
A porous organic polymer (POP) with chiral 2,2'-bis(diphenylphosphino)-1,1'-binaphthalene (BINAP) has been prepared and characterized by several techniques including ¹³C CP/MAS NMR, ³¹P CP/MAS NMR, fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption. The material exhibits amorphous microporous structure. After loading of ruthenium(Ⅱ) species via coordination, the composite material Ru/POP-BINAP could be used as a heterogeneous catalyst for the asymmetric hydrogenation of β-keto esters with high activity, excellent enantioselectivity and recyclability.
Key words: porous organic polymer, heterogeneous catalysis, asymmetric hydrogenation, β-keto esters


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