摘要/Abstract
3，4-二甲基-1-苯基磷杂环戊二烯通过两次[1，5]σ-迁移在α-位分别引入苯基和亚胺基得到α-亚胺基磷杂环戊二烯负离子1，1和[Cp*FeCl]n反应得到新的P，N双齿配体α-亚胺基磷杂二茂铁2.2可以和Mo和Rh等形成配合物，其中2及其Mo配合物的结构由X射线单晶衍射确定.
关键词: 磷杂二茂铁, 亚胺, 配位化学
An 2-iminophospholide 1 can be obtained via two [1,5] shifts by reaction of potassium tert-butoxide with 3,4-di- methyl-1-phenylphosphole and an imidoyl chloride. The reaction of 1 with [Cp*FeCl]n affords a 2-iminophosphaferrocene 2 which behaves as a P,N chelating ligand toward Mo(CO)4 and Rh(CO)2]+. The X-ray crystal structures of 2 and its Mo complex have been recorded.
Key words: phosphaferrocene, imine, coordination chemistry
PDF全文下载地址:
点我下载PDF
