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化学与分子工程学院??????


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开授课程
科研项目
学术成果
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个人资料
部门： 化学与分子工程学院
毕业院校：
学位：
学历：
邮编：
联系电话：
传真：
电子邮箱： dxing@sat.ecnu.edu.cn
办公地址： 上海市中山北路3663号华东师范大学理科大楼B1517室
通讯地址： 上海市中山北路3663号华东师范大学理科大楼B1517室

教育经历
2006.09-2011.02： 香港大学 博士
1999.09-2006.06：
华东师范大学
学士、硕士





工作经历
2015.12-至今： 华东师范大学 副研究员
2016.06-2018.01：
美国芝加哥大学
博士后
2016.01-2016.05： 美国德克萨斯大学奥斯汀分校 博士后
2012.06-2015.12：
华东师范大学 晨晖****
2011.03-2012.03： 香港大学 研究助理


个人简介

社会兼职


研究方向
有机合成方法学研究；多样性导向的小分子化合物库的构建及相关药物化学研究



开授课程


科研项目


学术成果

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26.
Li, J.; Ma, C.; Xing, D.*; Hu, W.*Catalyst-Free gem-Difunctionalization of Fluoroalkyl-Substituted Diazo Compound with Diselenide or Disulfide and NFSI. Org. Lett.2019, 21, 2101-2105



25.
Xing D.;Qi X.; Marchant D.,; Liu P.*; Dong G.*Branched-SelectiveDirecta-AlkylationofCyclicKetoneswithSimple Alkenes.Angew. Chem. Int. Ed.2019,58, 4366-4370



24.
Alavala, G. K. R.; Sajjad, F.; Shi, T.; Kang, Z.; Ma, M.; Xing, D.*; Hu, W.* Diastereoselective synthesis of isochromans via the Cu(II)-catalysed intramolecular Michael-type trapping of oxonium ylides. Chem. Commun.2018, 54, 12650-12653.



23.
Chen. T; Yang, Y. Xie, L.; Yang, H.; Dong, G.*; Xing, D.*Ni(0)-Catalyzed α-Allylic Alkylation of Regular Ketones with 1,3-Dienes under pH and Redox-neutral Conditions" ChemRxiv.Preprint. [doi]



22.
Lv, X.; Kang, Z.; Xing, D.*; Hu, W.* Cu(I)-Catalyzed Three-Component Reaction of Diazo Compound with Terminal Alkyne and Nitrosobenzene for the Synthesis of Trifluoromethyl Dihydroisoxazoles. Org. Lett.,2018,20(16),pp 4843–4847



21.
Xiao, G.; Chen, T.; Ma, C.;Xing, D.*; Hu, W.*Rh(II)/Chiral Phosphoric Acid-Cocatalyzed Enantioselective Synthesis of Spirooxindole-Fused Thiaindans. Org. Lett.,2018,20(16),pp 4531–4535



20.
Xiao, G.; Ma, C.; Wu, X.;Xing, D.*; Hu, W.*Synthesis of γ-Sulfur-Substituted Ketones via Rh(II)/Sc(III) Cocatalyzed Three-Component Reaction of Diazo Compounds with Thiophenols and Enones.J. Org. Chem.2018,83(8),pp 4786–4791



19.
Xing, D.; Dong, G.* Branched-Selective Intermolecular Ketonea-Alkylation with Unactivated Alkenes via An Enamide Directing Strategy.J. Am. Chem. Soc.2017,139, 13664-13667



18.
Xiao, G.; Ma,C.;Xing, D.*; Hu, W.* Enantioselective Synthesisof α-Mercapto-β-amino Esters via Rh(II)/Chiral Phosphoric Acid-CocatalyzedThree-Component Reaction of Diazo Compounds, Thiols, and Imines.Org.Lett.2016, 18, 6086-6089Highlighted bySynfacts,2017,13(02), 0181



17.
Ma, C.;Xing, D.*; Hu, W.* Catalyst-Free Halogenation of α-Diazocarbonyl Compounds withN-Halosuccinimides: Synthesis of 3-Halooxindoles or Vinyl Halides.Org. Lett.2016,18(13), 3134-3137



16.
Che, J.;Xing, D.*; Hu, W.* Metal-Catalyzed Cross-Coupling of Terminal Alkynes with Different Carbene Precursors.Curr. Org. Chem.2016,20 (1), 41-60.Invited Review



15.
Jing, C.;Xing, D.*; Gao, L.; Li, J.; Hu, W.* Divergent Synthesis of Multisubstituted Tetrahydrofurans and Pyrrolidines via Intramolecular Aldol-type Trapping of Onium Ylide IntermediatesChem.--Eur. J.2015,21, 19202-19207Highlighted bySynfacts,2016,12(02), 0136



14.
Jing, C.;Xing, D.*; Hu, W.* Catalytic Asymmetric Four-Component Reaction for the Rapid Construction of 3,3-Disubstituted 3?Indol-3’-yloxindoles.Org. Lett.2015,17(17), 4336-4339



13.
Tang, M.;Xing, D.*; Huang, H.; Hu, W.* Divergent synthesis of chiral heterocycles via sequencing of enantioselective three-component reactions and one-pot subsequent cyclization reactions.Chem. Commun.2015,51(53), 10612-10615 (Inside front cover)Highlighted bySynfacts,2015,11(10), 1074. Front Cover.



12.
Jing, C.;Xing, D.*; Hu, W.* Synthesis of 3-(hydroxymethyl)-3-indol-3`-yloxindolesviaRh(II)-catalyzed three-component reaction of 3-diazooxindoles, indoles and formalin.Tetrahedron2015,71(22), 3597-3602.



11.
Jia, S.;Xing, D.*; Zhang, D; Hu, W.* Catalytic Asymmetric Aromatic C–H Functionalization via Electrophilic Trapping of Active Zwitterionic Intermediate.Angew. Chem. Int. Ed.2014,53(48), 13098-13101.Highlighted bySynfacts,2014,10(11), 1171Front Cover



10.
Zhai,C.;Xing, D.*; Jing, C.; Zhou, J.; Wang, C.; Wang, D.; Hu, W.* Facile Synthesis of 3-Aryloxindoles via Br?nsted Acid Catalyzed Friedel–Crafts Alkylation of Electron-Rich Arenes with 3-Diazooxindoles.Org. Lett.2014,16(11), 2934-2937.



9.
Wang, C.;Xing, D.*; Wang, D.; Wu, X.; Hu, W.* Synthesis of 3-Amino-3-hydroxymethyloxindoles and 3-Hydroxy-3-hydroxymethyloxindoles by Rh₂(OAc)₄-Catalyzed Three-Component Reactions of 3-Diazooxindoles with Formaldehyde and Anilines or Water.J. Org. Chem.2014,79 (9),3908-3916.



8.
Zhai, C.;Xing, D.*; Qian, Y.; Ji, J.; Ma, C.; Hu, W.* Trapping of Carboxylic Oxonium Ylides with N-Boc Imines for the Facile Synthesis ofb-Amino Alcohol Derivatives.Synlett2014,25, 1745-1750.



7.
Xing, D.; Hu, W.* Recent advances in metal carbenoid mediated nitrogen-containing zwitterionic intermediate trapping process.Tetrahedron Lett.2014,55(4), 777-783.



6.
Xing, D.*; Jing, C.; Li, X.; Qiu, H.; Hu, W.* Highly Efficient Synthesis of Mixed 3,3′-BisindolesviaRh(II)-Catalyzed Three-Component Reaction of 3-Diazooxindoles with Indoles and Ethyl Glyoxylate.Org. Lett.2013,15, 3578-3581.Highlighted bySynfacts,2013,9(10), 1078

?

?5.
Ma, C.;Xing, D.*; Zhai, C.; Che, J.; Liu, S.; Wang, J.; Hu, W.* Iron Porphyrin-Catalyzed Three-Component Reaction of Ethyl Diazoacetate with Aliphatic Amines and β,γ-Unsaturated α-Keto Esters.Org. Lett.2013,15, 6140-6143



4.
Jing, C.;Xing, D.; Hu, W.* Highly diastereoselective synthesis of 3-hydroxy-2,2,3-trisubstituted indolines via intramolecular trapping of ammonium ylides with ketones.Chem. Commun.2014,50, 951-953

3.
Jing, C.;Xing, D.; Qian, Y.; Hu, W., Rh₂(OAc)₄and Chiral Phosphoric Acid Cocatalyzed Highly Diastereo- and Enantioselective Four-Component Reactions: Facile Synthesis of Chirala,b-Diamino Acid Derivatives.Synthesis2014,46, 1348-1354

2.
Jing, C.;Xing, D.; Qian, Y.; Shi, T.; Zhao, Y.; Hu, W.* Diversity-Oriented Three-Component Reactions of Diazo Compounds with Anilines and 4-Oxo-Enoates.Angew. Chem. Int. Ed.2013,52, 9289-9292

1.
Jing, C.; Shi, T.;Xing, D.; Guo, X.; Hu, W.* CuSO₄catalyzed three-component reaction of α-diazo ester, water and isatin: an efficient approach to oxindole derivatives.Green Chem.,2013,15,620


Previous work:
Xing, D.; Yang, D.* Pd(II)-Catalyzed Intramolecular 1,2-Aminoalkylation of Conjugated 1,3-Dienes for the Synthesis of Pyrrolizidines. Org. Lett. 2013,15, 4370-4373.
Xing, D.; Yang, D.*, Gold(I)-Catalyzed Decarboxylative Allylic Amination of Allylic N-Tosylcarbamates. Org. Syn.2012, 89, 450
Xing D.; Yang, D.*, Gold(I)-Catalyzed Highly Efficient Overman Rearrangement in Water. Beilstein J. Org. Chem.2011, 7, 781-785.
Xing, D.; Yang, D.*, Gold(I)-Catalyzed Highly Regio- and Stereoselective Decarboxylative Amination of Allylic N-Tosylcarbamates viaBase-Induced Aza-Claisen Rearrangement in Water. Org. Lett.2010, 12 (5), 1068-1071.
Xing, D.; Xu, X. F.; Yang, L. P.*, Highly Chemoselective Rearrangement of 3-Aryloxaziridines to Nitrones or Amides. Synthesis-Stuttgart2009, (20), 3399-3404.
Xing, D.; Guan, B. T.; Cai, G. X.; Fang, Z.; Yang, L. P.; Shi, Z. J.*, Gold(I)-Catalyzed Oxidative Cleavage of a C-C Double Bond in Water. Org. Lett. 2006, 8 (4), 693-696.
Wan, X. B.; Xing, D.; Fang, Z.; Li, B. J.; Zhao, F.; Zhang, K. Y.; Yang, L. P.; Shi, Z. J.*, Multiple Deprotonations and Deaminations of Phenethylamines to Synthesize Pyrroles. J. Am. Chem. Soc.2006, 128 (37), 12046-12047.

Guan, B. T.; Xing, D.; Cai, G. X.; Wan, X. B.; Yu, N.; Fang, Z.; Yang, L. P.; Shi, Z. J.*, Highly Selective Aerobic Oxidation of Alcohol Catalyzed by a Gold(I) Complex with an Anionic Ligand. J. Am. Chem. Soc.2005, 127 (51), 18004-18005.





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