石佳奇1,2,
陈樯1,2,,,
龙涛1,2
1. 生态环境部南京环境科学研究所, 南京 210042;
2. 国家环境保护土壤环境管理与污染控制重点实验室, 南京 210042
作者简介: 杨璐(1990-),女,博士,研究方向为生态毒理学,E-mail:yanglu@nies.org.
通讯作者: 陈樯,chenqiang@nies.org ;
基金项目: 国家重点研发计划资助项目(2018YFC1801100)中图分类号: X171.5
Human Health Risk Assessment of Petroleum Hydrocarbons in Contaminated Sites from the Perspective of Components and Properties
Yang Lu1,2,Shi Jiaqi1,2,
Chen Qiang1,2,,,
Long Tao1,2
1. Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, China;
2. State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control, Nanjing 210042, China
Corresponding author: Chen Qiang,chenqiang@nies.org ;
CLC number: X171.5
-->
摘要
HTML全文
图
参考文献
相关文章
施引文献
资源附件
访问统计
摘要:石油烃的人体健康风险评估是污染地块土壤污染风险评估过程中的最常见的问题之一,其远比单一污染物的评估复杂和困难。但我国缺乏针对性的评估方法,实际操作中存在较多误区。因此,对于石油烃概念、性质的归纳总结以及对其健康风险评估方法的研究和探索,具有重要的意义。本文介绍了石油烃的基本概念,分析了不同馏分性质间的关系,回顾并分析了其分析测试方法及人体健康风险评估方法的适用要求及优缺点,提出了指示剂法与分馏法相结合采用典型样品馏分占比进行总体评估的工作方法,进而针对我国当前面临的问题,提出了后续的研究和发展建议。
关键词: 石油烃/
土壤/
慢性毒性/
人体健康风险/
风险评估方法
Abstract:Human health risk assessment of petroleum hydrocarbons is a common problem in the process of risk assessment of contaminated sites, and it is far more complicated and challenging than the assessment of single pollutants. Currently in China, specific assessment methods for petroleum hydrocarbons have not been established, and misunderstandings in the practice of risk assessment concerning this group of contaminants are common. Therefore, it is important to summarize the concepts and properties of petroleum hydrocarbons, and to study and explore their health risk assessment methods. This paper introduces the basic concepts of petroleum hydrocarbons, analyzes the relationship between the properties of different fractions, reviews and analyzes the applicable requirements, advantages and disadvantages of their analytical methods and human health risk assessment methods, proposes the working method of overall assessment by combining indicator method and fractionation method using typical sample fraction percentages, and puts forward suggestions for further research and development based on the current challenges.
Key words:petroleum hydrocarbons/
soil/
chronic toxicity/
human health risk/
risk assessment methods.
刘丹青. 我国污染场地土壤石油烃环境质量标准体系的现状与趋势[J]. 中国环境监测, 2020, 36(1):138-146Liu D Q. Current situation and trend of petroleum hydrocarbon related standard system in contaminated site soils of China[J]. Environmental Monitoring in China, 2020, 36(1):138-146(in Chinese) |
黄雪洋. 污染场地地下水中石油烃的生物强化降解及风险管控研究[D]. 北京:中国地质大学(北京), 2020:1-2 Huang X Y. Research on biodegradation and risk control of petroleum hydrocarbon in groundwater at a contaminated site[D]. Beijing:China University of Geosciences, 2020:1-2(in Chinese) |
中华人民共和国生态环境部. 建设用地土壤污染风险评估技术导则:HJ 25.3-2019[S]. 北京:中国环境出版集团, 2020 Ministry of Ecology and Environment of the People's Republic of China. Technical guidelines for risk assessment of soil contamination of land for construction:HJ 25.3-2019[S]. Beijing:China Environmental Science Press, 2020(in Chinese) |
中华人民共和国生态环境部. 土壤环境质量建设用地土壤污染风险管控标准:GB36600-2018[S]. 北京:中国环境出版集团, 2019 Ministry of Ecology and Environment of the People's Republic of China. Soil environmental quality risk control standard for soil contamination of development land:GB36600-2018[S]. Beijing:China Environmental Science Press, 2019(in Chinese) |
中华人民共和国生态环境部. 工业企业场地环境调查评估与修复工作指南(试行)[S]. 北京:中华人民共和国生态环境部, 2014 |
中华人民共和国生态环境部. 建设用地土壤环境调查评估技术指南[S]. 北京:中华人民共和国生态环境部, 2017 |
上海市生态环境局. 沪环土[2020] 62号上海市建设用地土壤污染状况调查、风险评估、风险管控与修复方案编制、风险管控与修复效果评估工作的补充规定(试行)[S]. 上海:上海市生态环境局, 2020 |
陈捷. 石油烃组分在土壤和地下水环境中的分布规律与迁移特征研究[D]. 广州:华南理工大学, 2018:3-5 Chen J. Distribution and migration characteristics of petroleum hydrocarbon components in soil and groundwater environment[D]. Guangzhou:South China University of Technology, 2018:3-5(in Chinese) |
Adeniji A O, Okoh O O, Okoh A I. Analytical methods for the determination of the distribution of total petroleum hydrocarbons in the water and sediment of aquatic systems:A review[J]. Journal of Chemistry, 2017, 2017:1-13 |
Weisman W, Vorhees D. Human Health Risk-Based Evaluation of Petroleum Contaminated Site:Implementation of the Working Group Approach[M]. Amherst:Amherst Scientific Publishers, 1998:27-28 |
Potter T L, Simmons K E. Total petroleum hydrocarbon criteria working group series:Volume 2:Composition of petroleum mixtures[R]. Amherst:Total Petroleum Hydrocarbon Criteria Working Group Series, 1998 |
Rojo F. Degradation of alkanes by bacteria[J]. Environmental Microbiology, 2009, 11(10):2477-2490 |
吴慧君, 宋权威, 郑瑾, 等. 微生物降解石油烃的功能基因研究进展[J]. 微生物学通报, 2020, 47(10):3355-3368Wu H J, Song Q W, Zheng J, et al. Function genes in microorganisms capable of degrading petroleum hydrocarbon[J]. Microbiology China, 2020, 47(10):3355-3368(in Chinese) |
Varjani S J. Microbial degradation of petroleum hydrocarbons[J]. Bioresource Technology, 2017, 223:277-286 |
Edwards D A, Andriot M D, Amoruso M A, et al. Total Petroleum Hydrocarbon Criteria Working Group Series:Volume 4:Development of fraction specific reference doses (RfDs) and reference concentration (RfCs) for total petroleum hydrocarbons (TPH)[R]. Amherst:Total Petroleum Hydrocarbon Criteria Working Group Series, 1997 |
中华人民共和国国家卫生健康委员会. 生活饮用水卫生标准:GB 5749-2006[S]. 北京:中国标准出版社, 2007 National Health Commission of the People's Republic of China. Standards for drinking water quality:GB 5749-2006[S]. Beijing:Standards Press of China, 2007(in Chinese) |
万云洋, 朱迎佳, 费佳佳, 等. 环境中的多环芳烃结构及其危害[J]. 油气田环境保护, 2017, 27(6):23-26,56 Wan Y Y, Zhu Y J, Fei J J, et al. The structure of polycyclic aromatic hydrocarbons and its danger in the environment[J]. Environmental Protection of Oil & Gas Fields, 2017, 27(6):23-26,56(in Chinese) |
陆凤翔, 杨玉. 临床实用药物手册[M]. 2版. 南京:江苏科学技术出版社, 2002:292 |
古文革, 杜丹, 王桂菊. 油田采出水中含油量和外排水中石油类、石油烃的差异分析[J]. 油气田地面工程, 2018, 37(3):89-92Gu W G, Du D, Wang G J. Differential analysis between oil content in oilfield produced water and petroleum and petroleum hydrocarbons in effluent[J]. Oil-Gas Field Surface Engineering, 2018, 37(3):89-92(in Chinese) |
杨慧娟. 土壤中石油烃分段测定方法及根际促生菌强化植物修复研究[D]. 南京:南京师范大学, 2013:3-5 |
United States Environmental Protection Agency (US EPA). SW-846 Test Method 8015C:Nonhalogenated Organics by Gas Chromatography[S]. Washington DC:US EPA, 2007 |
United States Environmental Protection Agency (US EPA). SW-846 Test Method 8260D:Volatile Organic Compounds by Gas Chromatography/Mass Spectrometry (GC/MS)[S]. Washington DC:US EPA, 2018 |
United States Environmental Protection Agency (US EPA). SW-846 Test Method 8270E:Semivolatile Organic Compounds by Gas Chromatography/Mass Spectrometry (GC/MS)[S]. Washington DC:US EPA, 2018 |
Texas Commission on Environmental Quality (TCEQ). Total Petroleum Hydrocarbons TNRCC Method 1005[S]. Austin:TCEQ, 2001 |
Texas Commission on Environmental Quality (TCEQ). Draft TNRCC Method 1006[S]. Austin:TCEQ, 2000 |
Washington State Department of Ecology. Analytical Methods for Petroleum Hydrocarbons. Publication No. ECY 97-602:137.[S]. Lacey:Washington State Department of Ecology, 1997 |
Massachusetts Department of Environmental Protection (MassDEP). Method for the Determination of Extractable Petroleum Hydrocarbons (EPH)[S]. Boston:MassDEP, 2004 |
Massachusetts Department of Environmental Protection (MassDEP). Method for the Determination of Volatile Petroleum Hydrocarbons (VPH) by Gas Chromatography/Mass Spectrometry[S]. Boston:MassDEP, 2004 |
Massachusetts Department of Environmental Protection (MassDEP). Method for the Determination of Volatile Petroleum Hydrocarbons (VPH) by Gas Chromatography/Photoionization Detector/Flame Ionization Detector[S]. Boston:MassDEP, 2004 |
United States Environmental Protection Agency (US EPA). SW-846 Test Method 3630C:Silica Gel Cleanup[S]. Washington DC:US EPA, 2018 |
中华人民共和国生态环境部. 土壤和沉积物石油烃(C6-C9)的测定吹扫捕集/气相色谱法:HJ 1020-2019[S]. 北京:中国环境出版集团, 2020 Ministry of Ecology and Environment of the People's Republic of China. Soil and sediment-Determination of petroleum hydrocarbons(C6-C9)-Purge and trap/gas chromatography:HJ 1020-2019[S]. Beijing:China Environmental Science Press, 2020(in Chinese) |
中华人民共和国生态环境部. 土壤和沉积物石油烃(C10-C40)的测定气相色谱法:HJ 1021-2019[S]. 北京:中国环境出版集团, 2020 Ministry of Ecology and Environment of the People's Republic of China. Soil and sediment-Determination of petroleum hydrocarbons (C10-C40)-Gas chromatography:HJ 1021-2019[S]. Beijing:China Environmental Science Press, 2020(in Chinese) |
李桂香, 高岩, 张青. 环境样品中石油烃的分类/分段检测技术[J]. 实验室研究与探索, 2016, 35(4):30-33Li G X, Gao Y, Zhang Q. Testing technology of total petroleum hydrocarbon speciation/fractions in the environmental samples[J]. Research and Exploration in Laboratory, 2016, 35(4):30-33(in Chinese) |
中华人民共和国生态环境部. 关于征求《土壤石油类的测定红外光度法》等七项国家环境保护标准意见的函. (2018-09-12). http://www.mee.gov.cn/gkml/sthjbgw/stbgth/201809/t20180921_626427.htm. |
中华人民共和国生态环境部. 关于征求《水质石油类的测定紫外分光光度法(征求意见稿)》等三项国家环境保护标准意见的函. (2018-05-30). http://www.mee.gov.cn/gkml/sthjbgw/stbgth/201806/t20180601_442260.htm. |
谢楠, 徐佼姣. 水质中石油类(红外分光光度法)与石油烃(GC_MS和GC_FID)的检测结果比较[J]. 资源节约与环保, 2015(3):93-94 |
李晶晶, 白光明, 于瀛鑫. GC-MS法与红外分光光度法测定水中石油类烃含量的方法比对[J]. 黑龙江科技信息, 2017(4):156-157 |
McMillen S J. Risk-Based Decision-Making for Assessing Petroleum Impacts at Exploration and Production Sites[M]. Washington DC:Department of Energy, 2001 |
Zemo D A. White paper:Analytical methods for total petroleum hydrocarbons (TPH)[R]. Washington DC:American Petroleum Institute (API), 2016 |
Interstate Technology and Regulatory Council (ITRC). TPH risk evaluation at petroleum-contaminated sites[R]. Washington DC:ITRC, 2018 |
にほん環境省. 環境庁告示第46号, 土壌の汚染に係る環境基準[S]. とうきよう:にほん環境省, 1991 Ministry of the Environment of Japan. Environment Agency Notification No. 46, Environmental Standard for Soil Contamination[S]. Tokyo:Ministry of the Environment of Japan, 1991(in Japanese) |
Bundesregierung. BGBl. I S. 1554, Federal Soil Protection and Contaminated Sites Ordinance(BBodSchV)[S]. Berlin:The Federal Republic of Germany, 1999 |
Yao Y J, Verginelli I, Suuberg E M. A two-dimensional analytical model of petroleum vapor intrusion[J]. Water Resources Research, 2016, 52(2):1528-1539 |
Yao Y J, Shen R, Pennell K G, et al. A review of vapor intrusion models[J]. Environmental Science & Technology, 2013, 47(6):2457-2470 |
Ma J, Lahvis M. Rationale for soil-gas sampling to improve vapor intrusion risk assessment in China[J]. Groundwater Monitoring & Remediation, 2020, 40:12-13 |
Beckley L, McHugh T. A conceptual model for vapor intrusion from groundwater through sewer lines[J]. Science of the Total Environment, 2020, 698:134283 |
Yao Y J, Xiao Y T, Luo J, et al. High-frequency fluctuations of indoor pressure:A potential driving force for vapor intrusion in urban areas[J]. Science of the Total Environment, 2020, 710:136309 |
Idowu O, Kim Anh Tran T, Baker P, et al. Bioavailability of polycyclic aromatic compounds[J]. Science of the Total Environment, 2020, 736:139574 |
Liu X L, Ji R, Shi Y, et al. Release of polycyclic aromatic hydrocarbons from biochar fine particles in simulated lung fluids:Implications for bioavailability and risks of airborne aromatics[J]. Science of the Total Environment, 2019, 655:1159-1168 |
Gao P, da Silva E B, Townsend T, et al. Emerging PAHs in urban soils:Concentrations, bioaccessibility, and spatial distribution[J]. Science of the Total Environment, 2019, 670:800-805 |
Ministry of Infrastructure and Water Management of the Netherlands. Soil Remediation Circular 2013[S]. Bilthoven:Ministry of Infrastructure and Water Management of the Netherlands, 2013 |
United States Environmental Protection Agency (US EPA). Regional Screening Levels (RSLs) Risk Assessment.. https://www.epa.gov/risk/regional-screening-levels-rsls. |
National Institute for Public Health and the Environment (RIVM). A proposal for revised intervention values for petroleum hydrocarbons (mineral oil) on base of fractions of petroleum hydrocarbons. RIVM report 711701015[R]. Bilthoven:RIVM, 1999 |
中国台湾地区环境保护局. 土壤污染管制标准[S]. 台北:中国台湾地区环境保护局, 2011 |
曹云者, 施烈焰, 李丽和, 等. 石油烃污染场地环境风险评价与风险管理[J]. 生态毒理学报, 2007, 2(3):265-272Cao Y Z, Shi L Y, Li L H, et al. Petroleum hydrocarbons-contaminated sites and related risk-based management strategy[J]. Asian Journal of Ecotoxicology, 2007, 2(3):265-272(in Chinese) |
Ministry for the Environment of New Zealand. Guidelines for assessing and managing petroleum hydrocarbon contaminated sites in New Zealand. ME 1074.[S]. Wellington, New Zealand:Ministry for the Environment of New Zealand, 1997 |
Environment Agency. Principles for evaluating the human health risks for petroleum hydrocarbons in soils:A consultation paper[J]. R&D Technical Report, 2003:1 |
Environment Agency of United Kingdom. Review of comments on:Environment Agency public consultation paper-Principles for evaluating the human health risks from petroleum hydrocarbons in soils. Science Report P5-080/TR2[R]. Bristol:Environment Agency of United Kingdom, 2004 |
Twerdok L E. Development of toxicity criteria for petroleum hydrocarbon fractions in the Petroleum Hydrocarbon Criteria Working Group approach for risk-based management of total petroleum hydrocarbons in soil[J]. Drug and Chemical Toxicology, 1999, 22(1):275-291 |