张少峰,
于硕
自然资源部第四海洋研究所, 北海 536000
作者简介: 张丽(1990-),女,博士,助理研究员,研究方向为海洋分析化学和生态环境化学,E-mail:lizhang.phd@hotmail.com.
通讯作者: 张丽,lizhang.phd@hotmail.com ;
基金项目: 广西科技基地和人才专项（桂科AD1910047）；北海市科技计划项目（北科合201995033）；自然资源部第四海洋研究所博士科研启动经费资助项目（201807）；广西重点研发计划资助项目（桂科AB1850023）中图分类号: X171.5
Organophosphorus Flame Retardents in Aquatic Environment: A Review on Occurrence, Bioaccumulation and Metabolism
Zhang Li,,Zhang Shaofeng,
Yu Shuo
Forth Institute of Oceanography, Ministry of Natural Resources, Beihai 536000, China
Corresponding author: Zhang Li,lizhang.phd@hotmail.com ;
CLC number: X171.5
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摘要:随着世界范围内对溴代阻燃剂的禁用，有机磷阻燃剂（OPFRs）被作为替代品广泛应用于建筑、纺织、化工、电子以及家装材料等行业，生产和使用量逐年上升。由于OPFRs在环境和生物体中普遍检出，且多种化合物具有致癌性、神经毒性和生殖毒性，对生态环境和人体健康造成潜在威胁，目前已成为国际上的一个研究热点。笔者重点综述了河流、湖泊和海洋等水体及沉积物中OPFRs污染现状，水生生物对OPFRs的生物富集和生物放大，以及OPFRs在水生生物体内和体外生物代谢的研究进展，并对目前该领域仍有待探讨的问题及研究趋势进行了展望。
关键词: 有机磷阻燃剂/
水环境/
污染现状/
生物富集/
生物转化
Abstract:With the worldwide prohibition of brominated flame retardants, organophosphorus flame retardants (OPFRs) are widely used as alternatives in construction, textile, chemical, electronics and home improvement material industries. OPFRs are frequently detected in the environment and organisms. Such compounds are potential threat to the ecological environment and human health due to carcinogenicity, neurotoxicity and reproductive toxicity. Therefore, there is an increasing concern for OPFRs and it has become one of the hotspots in environmental research area. The present review outlines the occurrence of OPFRs in river water, lake water, seawater and sediments as well as the bioaccumulation and biomagnification effects by aquatic organisms. The in vivo and in vitro metabolism of OPFRs in fish is also described. Finally, knowledge gaps and future perspectives on OPFRs are identified.
Key words:organophosphorus flame retardants (OPFRs)/
aquatic environment/
pollution status/
bioaccumulation/
biotransformation.
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