PVC-MnO2的制备及其对锂离子的吸附行为

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王宏岩1，黄凯1*，张玉生3，郑诗礼2，张懿2，李平2

1. 北京科技大学冶金与生态工程学院，北京 100083
2. 中国科学院过程工程研究所湿法冶金清洁生产技术国家工程实验室，北京 100190
3. 山东钢铁济钢合金科技有限公司，山东济南 250000

收稿日期:2017-10-16修回日期:2017-12-08出版日期:2018-08-22发布日期:2018-08-15
通讯作者:黄凯

基金资助:亚熔盐法处理低品位硼镁矿制备过硼酸钠清洁化工新过程的基础研究

Preparation of PVC-MnO₂ and its adsorption behavior to Li ion

Hongyan WANG1, Kai HUANG1*, Yusheng ZHANG3, Shili ZHENG2, Yi ZHANG2, Ping LI2

1. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijng 100083, China
2. National Engineering Lab for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering,
Chinese Academy of Sciences, Beijing 100190, China
3. Shandong Steel Jisteel Alloy Technology Co., Ltd., Jinan, Shandong 250000, China

Received:2017-10-16Revised:2017-12-08Online:2018-08-22Published:2018-08-15
Contact:Kai -HUANG

摘要/Abstract

摘要： MnCO3和Li2CO3经高温煅烧合成Li4Mn5O12，再与聚氯乙烯(PVC)和N,N-二甲基甲酰胺溶液混合，干燥、酸洗后制得粒径3?4 mm的多孔球形PVC?MnO2锂离子筛，用其吸附Li离子. 结果表明，PVC?MnO2吸附Li离子的反应符合Langmuir方程和拟二级动力学方程，吸附焓变为0.358 kJ/mol，吸附反应为吸热反应，Li离子最高吸附量可达23.4 mg/g.

引用本文

王宏岩黄凯张玉生郑诗礼张懿李平. PVC-MnO₂的制备及其对锂离子的吸附行为[J]. 过程工程学报, 2018, 18(4): 821-827.
Hongyan WANG Kai HUANG Yusheng ZHANG Shili ZHENG Yi ZHANG Ping LI. Preparation of PVC-MnO₂ and its adsorption behavior to Li ion[J]. Chin. J. Process Eng., 2018, 18(4): 821-827.

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参考文献

[1]李法强. 世界锂资源提取技术述评与碳酸锂产业现状及发展趋势[J].世界有色金属, 2015, 5: 17-23.
[2]Ling C, Zhang R, Takechi K, et al. Intrinsic barrier to electrochemically decompose Li2CO3 and LiOH[J]. J. Phys. Chem. C. 2014, 118(46): 26591-26598.
[3]Rahman M A, Wang X, Wen C. A review of high energy density lithium–air battery technology[J]. J. Appl. Electrochem. 2014, 44(1): 5-22.
[4]何启贤. 世界锂金属资源开发利用现状及其市场前景分析[J]. 轻金属, 2011, 9: 3-7.
[5]胡兴军. 锂:市场前景极为广阔[J]. 中国金属通报, 2011, 9: 26-28.
[6]谢贞付, 王毓华, 于福顺, 等. 伟晶岩型锂辉石矿浮选研究综述[J]. 稀有金属, 2013, 4: 641-649.
[7]Gruber P W, Medina P A, Keoleian G A, et al. Global lithium availability[J]. J. Ind. Ecol. 2011, 15(5): 760-775.
[8]Liu L, Zhang H, Zhang Y, et al. Lithium extraction from seawater by manganese oxide ion sieve MnO2?0.5H2O[J]. Colloids Surf., A : Physicochemical and Engineering Aspects, 2015, 468: 280-284.
[9]Wang L, Ma W, Liu R, et al. Correlation between Li+ adsorption capacity and the preparation conditions of spinel lithium manganese precursor[J]. Solid State Ionics, 2006, 177(17): 1421-1428.
[10]Chitrakar R, Kanoh H, Miyai Y, et al. Recovery of lithium from seawater using manganese oxide adsorbent (H1.6Mn1.6O4) derived from Li1.6Mn1.6O4[J]. Ind. Eng. Chem. Res. 2001, 40(9): 2054-2058.
[11]Ryu T, Ryu J C, Shin J, et al. Recovery of lithium by an electrostatic field-assisted desorption process[J]. Ind. Eng. Chem. Res. 2013, 52(38): 13738-13742.
[12]Xiao J L, Sun S Y, Wang J, et al. Synthesis and adsorption properties of Li1.6Mn1.6O4 spinel[J]. Ind. Eng. Chem. Res. 2013, 52(34): 11967-11973.
[13]Zhang Q H, Li S P, Sun S Y, et al. Lithium selective adsorption on 1-D MnO2 nanostructure ion-sieve[J]. Adv. Powder Technol. 2009, 20(5): 432-437.
[14]Xiao G, Tong K, Zhou L, et al. Adsorption and desorption behavior of lithium ion in spherical PVC–MnO2 ion sieve[J]. Ind. Eng. Chem. Res. 2012, 51(33): 10921-10929.
[15]Umeno A, Miyai Y, Takagi N, et al. Preparation and adsorptive properties of membrane-type adsorbents for lithium recovery from seawater[J]. Ind. Eng. Chem. Res. 2002, 41(17): 4281-4287.
[16]Park M J, Nisola G M, Beltran A B, et al. Recyclable composite nanofiber adsorbent for Li+ recovery from seawater desalination retentate[J]. Chem. Eng. J. 2014, 254: 73-81.
[17]Xiao J L, Sun S Y, Song X, et al. Lithium ion recovery from brine using granulated polyacrylamide–MnO2 ion-sieve[J]. Chem. Eng. J. 2015, 279: 659-666.
[18]Zhu G, Wang P, Qi P, et al. Adsorption and desorption properties of Li+ on PVC-H1.6Mn1.6O4 lithium ion-sieve membrane[J]. Chem. Eng. J. 2014, 235: 340-348.
[19]Hong H J, Park I S, Ryu T, et al. Granulation of Li1.33Mn1.67O4 (LMO) through the use of cross-linked chitosan for the effective recovery of Li+ from seawater[J]. Chem. Eng. J. 2013, 234: 16-22.
[20]Xiao J, Nie X, Sun S, et al. Lithium ion adsorption–desorption properties on spinel Li4Mn5O12 and pH-dependent ion-exchange model[J]. Adv. Powder Technol. 2015, 26(2): 589-594.
[21]Li P, Zheng S L, Qing P H, et al. The vanadate adsorption on a mesoporous boehmite and its cleaner production application of chromate[J]. Green Chem, 2014, 16(9):4214-4222.
[22]Granadoscorrea F, Jiménezbecerril J. Chromium (VI) adsorption on boehmite[J]. J. Hazard. Mater, 2009, 162(2–3):1178-1184.
[23]Wang S L, Li P, Cui W W, et al. Hydrothermal synthesis of lithium-enriched β-Li2TiO3 with an ion-sieve application: excellent lithium adsorption[J]. Rsc Advances, 2016, 6(104):102608-102616.
[24]Naiya T K, Bhattacharya A K, Das S K. Removal of Cd(II) from aqueous solutions using clarified sludge[J]. J. Colloid Interface Sci, 2008, 325(1):48-56.
[25]Ho Y S, Mckay G. A Comparison of chemisorption kinetic models applied to pollutant removal on various sorbents[J]. Process Saf. Environ. Prot, 1998, 76(4):332-340.
[26]Shu J X, Wang Z H, Huang Y J, et al. Adsorption removal of Congo red from aqueous solution by polyhedral Cu2O nanoparticles: Kinetics, isotherms, thermodynamics and mechanism analysis[J]. J. Alloys Compd, 2015, 633(5):338-346.
[27]Zhou L M, Wang Y P, Liu Z R, et al. Characteristics of equilibrium, kinetics studies for adsorption of Hg(II), Cu(II), and Ni(II) ions by thiourea-modified magnetic chitosan microspheres[J]. J. Hazard. Mater, 2009, 161(2–3):995-1002.

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