gliu@tju.edu.cn
化学工程与技术
未公开
教授
军工项目5

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碳氢燃料主动冷却用HZSM-5纳米片涂层的可控制备与催化裂解性能

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碳氢燃料单分散纳米分子筛的可控制备与拟均相催化性能

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同步辐射真空紫外光电离质谱研究碳氢燃料催化热裂解机理

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超声速燃烧、流动与传热过程集成研究

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主动冷却用碳氢燃料可控吸热过程的关键问题

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军工项目1

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军工项目2

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军工项目3

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军工项目4

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油溶性单分散纳米分子筛的可控制备及拟均相催化性能

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重大专项

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先进燃料化学与过程

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重大专项

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催化碳氢燃料裂解用可溶纳米分子筛的制备与性能
提高喷气燃料裂解和安定性能的方法

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用于脱除喷气燃料中金属离子的分子筛吸附剂和制备方法

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用于吸热碳氢燃料裂解的改性纳米分子筛催化剂和制备方法

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包含航空飞行器发动机燃料的主动冷却剂及以该冷却剂对航空飞行器发动机进行冷却的方法

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一种超强酸包裹的HZSM-5分子筛催化剂、其制备方法和应用

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过氧化氢生产中蒽醌工作液氢化反应的操作方法

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同时提高分子筛催化剂涂层粘结强度和活性的方法

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本发明涉及一种包含航空飞行器发动机燃料的主动冷却剂，其包括在航空飞行器中分开储存的燃料油和H2O2水溶液。本发明还涉及将所述主动冷却剂对航空飞行器发动机进行冷却的方法，其包括以下步骤：向航空飞行器发动机的冷却通道中分别通入所述燃料油和所述H2O2水溶液，并通过调节所述H2O2水溶液的浓度使冷却通道内水蒸汽和燃料油中的碳的摩尔比以及氧气与燃料油中的碳的摩尔比维持在一定范围内；其中所述冷却通道中具有催化剂。

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本发明属于催化剂技术领域，具体公开了一种超强酸包裹的HZSM？5分子筛催化剂，即在HZSM？5分子筛表面包裹有超强酸TiO2·H2SO4、ZrO2·H2SO4、TiO2·H2S2O8或ZrO2·H2S2O8之一或组合物。本发明还公开了种超强酸包裹的HZSM？5分子筛催化剂的制备方法及其在石脑油催化裂解制备低碳烯烃工艺中的应用。

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本发明涉及一种过氧化氢生产中蒽醌工作液氢化反应的操作方法。属于蒽醌法生产过氧化氢技术。该方法采用固定床反应器，反应器内装填Pd/Al2O3催化剂，蒽醌工作液和氢气从反应器顶部加入，该方法的操作特征在于，氢气连续加入，蒽醌工作液周期加入，周期为10～400s，循环裂度为0.1～0.9；反应器的操作温度为40～70℃，操作压力为101.3～400.0kPa。

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本发明公开了一种同时提高分子筛催化剂涂层粘结强度和活性的方法。该方法过程包括：方法一：对载体表面作预处理，用含分子筛、二氧化硅粘合剂和无水乙醇的涂覆液涂覆载体，再在有机胺和水的蒸气中化学处理；方法二：对载体表面作预处理，用含分子筛、二氧化硅粘合剂、无水乙醇及季铵碱或季铵盐的涂覆液涂覆载体，再在水的蒸气中化学处理，得到分子筛催化剂涂层。该方法制备过程简单，通过涂覆次数和控制涂覆液的浓度可以控制涂层的厚度和负载量，以此方法制备的分子筛催化剂涂层具有粘结强度高和催化活性高的特点。
Synthesis and performance of pillared HZSM-5 nanosheet zeolites for ndecane catalytic cracking to produce light olefins

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Steam reforming of n-dodecane over mesoporous alumina supported nickel catalysts: Effects of metal-support interaction on nic

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Catalytic combustion of VOC on sandwich-structured Pt@ZSM-5 nanosheets prepared by controllable intercalation

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High pressure pyrolysis mechanism and kinetics of a strained-caged hydrocarbon fuel quadricyclane

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Superiority of ZrO2 surface enrichment on ZSM-5 zeolites in n-pentane catalytic cracking to produce light olefins

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Thermal Cracking of Endothermic Hydrocarbon Fuel in Regenerative Cooling Channels with Different Geometric Structures

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Controllable Fabrication and Catalytic Performance of Nanosheet HZSM-5 Films by Vertical Secondary Growth

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Reaction pathways of n-pentane cracking on the fresh and regenerated Sr, Zr and La-loaded ZSM-5 zeolites

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Analysis of reaction pathways for n-pentane cracking over zeolites to produce light olefins

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Effects of regeneration of ZSM-5 based catalysts on light olefins production in n-pentane catalytic cracking

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Catalytic Cracking of JP-10 over HZSM-5 Nanosheets

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SO42-/TiO2 promotion on HZSM-5 for catalytic cracking of paraffin

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Quantitative composition-property relationship of aviation hydrocarbon fuel based on comprehensive two-dimensional gas chroma

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Preparation of hydrocarbon dispersible HZSM-5 nanocrystals by hydrothermal crystallization of organofunctionalization seeds

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Binderless nano-HZSM-5 zeolite coatings prepared through combining washcoating and dry-gel conversion (DGC) methods

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Thermal Cracking of Hydrocarbon Aviation Fuels in Regenerative Cooling Microchannels

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Preparation and properties of hydrocarbon dispersible HZSM-5 nanocrystals for quasi-homogeneous catalytic cracking of n-dodecane

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Catalytic Cracking of Supercritical n-Dodecane over Wall-Coated HZSM-5 Zeolites with Micro- and Nanocrystal Sizes

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Preparation and Anticoking Performance of MOCVD Alumina Coatings for Thermal Cracking of Hydrocarbon Fuels under Supercritical Conditions

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Catalytic cracking of supercritical n -dodecane over wall-coated HZSM-5 zeolites with micro- and nanocrystal sizes

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Catalytic Cracking of Supercritical n-Dodecane over Wall-Coated HZSM-5 with Different Si/Al Ratios

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Supercritical thermal decompositions of normal- and iso-dodecane in tubular reactor

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Quasi-homogeneous catalytic activities of hydrocarbon dispersible HZSM-5 nanocrystals grafted with different alkyl groups

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On the Critical Points of Thermally Cracked Hydrocarbon Fuels under High Pressure

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Effect of HZSM-5 Coating Thickness upon Catalytic Cracking of n-Dodecane under Supercritical Condition

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New Method of Catalytic Cracking of Hydrocarbon Fuels Using a Highly Dispersed Nano-HZSM-5 Catalyst

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Catalytic cracking of n-dodecane over HZSM-5 zeolite under supercritical conditions: Experiments and kinetics

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Catalytic Cracking and Coking of Supercritical n-Dodecane in Microchannel Coated with HZSM-5 Zeolites

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Catalytic cracking and coking of supercritical n -dodecane in microchannel coated with HZSM-5 zeolites

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Catalytic performance of grafted Al-MCM-41 in hydroisomerization of n-dodecane

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High-temperature stabilizers for Chinese RP-3 jet fuels at 700 K

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Solid Deposits from Thermal Stressing of n-Dodecane and Chinese RP-3 Jet Fuel in the Presence of Several Initiators

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New insights into transient behaviors of local liquid-holdup in periodically operated trickle-bed reactors using electrical capacitance tomography (ECT)

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Oxidative Desulfurization of Jet Fuels and Its Impact on Thermal-Oxidative Stability

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Roles of Hydrogen Donors and Organic Selenides in Inhibiting Solid Deposits from Thermal Stressing of n-Dodecane and Chinese RP-3 Jet Fuel

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Thermal oxidative stabilities of endothermic fuel model compounds with pressure different scanning calorimeter

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Liquid-liquid equilibria for the ternary system water + methyl isobutyl ketone + tert-butyl alcohol at several temperatures

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Theoretical design and preparation of high thermal-stable jet fuel

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Unsteady-state operation of trickle-bed reactor for dicyclopentadiene hydrogenation

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Supercritical Thermal Cracking of N-Dodecane in Presence of Several Initiative Additives: Products Distribution and Kinetics

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Supercritical initiative cracking of endothermic fuel model compound n-dodecane with 1-nitroprapane