hxjiang@tju.edu.cn
未公开
研究员
VAM项目催化剂销售及使用-技术负责人

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具有纳米晶结构的MnOx-CeO2中空纳米球合成调控机制研究

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固定床电石乙炔法醋酸乙烯生产技术-催化剂子项

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生物乙醇制被乙烯基衍生物的生产技术-催化剂子项

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俄罗斯年产1万吨PVA及1.5万吨精甲酯生产技术工艺包-催化剂子项

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年产5万吨固定床电石乙炔法醋酸乙烯生产技术-催化剂子项

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精醋酸甲酯生产技术及固定床乙炔法醋酸乙烯催化剂单管试验研究-催化剂子项

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纳米晶Cu-Ce-Zr复合氧化物催化剂的SAS制备研究

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疏水型介孔炭基固体酸催化高酸值油脂合成生物柴油的降酸研究

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燃料乙醇项目（改扩建）精馏装置项目生产技术开发催化脱酸子项目

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山东龙口年产10万吨燃料乙醇、食用乙醇生产技术软件包及工程化子项目

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年产3.5万吨新戊二醇废水处理技术开发研究及工程化子项目
一种介孔碳基固体酸催化剂的制备方法及其应用

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采用超临界抗溶剂法对铈锆纳米复合氧化物微粒掺杂铜或锰的方法

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用超临界抗溶剂技术制备铈锆纳米复合氧化发明物微粒的方法

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生物丁醇生产过程的排杂方法

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气体分布器和包括所述气体分布器的醋酸乙烯合成反应器

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一种含氟介孔碳材料及其制备方法

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壳程结构和包括该壳程结构的列管式醋酸乙烯合成反应器

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超临界体系中酶催化制备甘油二酯的方法

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乙醇生产过程中催化反应精馏脱酸方法及装置

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杂醇油分子筛气相脱水方法及分离提纯方法
本发明涉及一种介孔碳基固体酸催化剂的制备方法及其应用。在酸性条件下，以糖类或低聚酚醛树脂等为碳源，借助超临界流体的特殊性质，采用超临界二氧化碳作为溶剂溶解碳源对二氧化硅模板进行浇铸填充，惰性气氛下高温炭化得到碳硅复合物，利用强酸或强碱溶液脱除二氧化硅铸型，后经酸改性得到介孔碳基固体酸催化剂。

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本发明涉及一种用超临界抗溶剂技术制备铈锆纳米复合氧化物微粒的方法。将铈盐和锆盐溶解在溶剂中，通过超临界流体的抗溶剂作用，在313～353K温度和7～40MPa压力下，使铈锆的可溶性盐类以组分均匀分散的纳米粒子的方式析出，得到铈锆纳米复合氧化物微粒的纳米前驱体颗粒；通过对前驱体的焙烧，得到纳米铈锆复合氧化物微粒。具有操作条件温和、过程易控、所得颗粒粒径小且粒径分布均匀、各复合组分分散均匀、所用的二氧化碳和溶剂可以重复使用等优点，是一种绿色环保的制备方法。

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本发明提出一种用超临界抗溶剂技术制备铈锆纳米复合氧化物颗粒的新方法，将盐类溶解在溶剂中，通过超临界流体的抗溶剂作用，在一定的温度和压力下，使铈锆的可溶性盐类以氢氧化物纳米粒子的方式析出，得到纳米铈锆纳米复合氧化物的前驱体，再通过对前驱体的焙烧，得到均匀的纳米铈锆复合氧化物微粒。该材料在汽车尾气处理催化剂、催化剂载体等方面具有广泛用途。

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生物丁醇生产过程的排杂方法

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气体分布器和包括所述气体分布器的醋酸乙烯合成反应器

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本发明涉及一种含氟介孔碳材料及其制备方法。

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壳程结构和包括该壳程结构的列管式醋酸乙烯合成反应器

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超临界体系中酶催化制备甘油二酯的方法

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乙醇生产过程中催化反应精馏脱酸方法及装置

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杂醇油分子筛气相脱水方法及分离提纯方法
Single-phase SO2-resistant to poisoning Co/Mn-MOF-74 catalysts for NH3-SCR.

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Morphology control of manganese-based catalysts for low-temperature selective catalytic reduction of NOx.

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The deactivation of a ZnO doped ZrO2-SiO2 catalyst in the conversion of ethanol/acetaldehyde to 1,3-butadiene

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Selective Catalytic Reduction of NOx with NH3 on Cu-BTC-derived Catalysts: Influence of Modulation and Thermal Treatment

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Catalytic activity of transition metal doped Cu(111) surfaces for ethanol synthesis from acetic acid hydrogenation: a DFT stu

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Catalytic activity of transition metal doped Cu(111) surfaces for ethanol synthesis from acetic acid hydrogenation: a DFT stu

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CeO2-ZrO2-Al2O3 Ternary Oxides Synthesized via Supercritical Anti-Solvent and as a Support for Pd Catalyst for CO Oxidation

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Effect of Cosolvent and Temperature on the Structures and Properties of Cu-MOF-74 in Low-temperature NH3-SCR.

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MOF-74 as an Efficient Catalyst for the Low-Temperature Selective Catalytic Reduction of NOx with NH3

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Synthesis of Highly Dispersed Ruthenium Nanoparticles Supported on Activated Carbon via Supercritical Fluid Deposition

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Controlled synthesis of highly dispersed and nano-sized Ru catalysts supported on carbonaceous materials via supercritical fl

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Investigation of Cu-Based Catalyst for Direct Synthesis of Ethyl Acetate from Ethanol: Improvement of Thermal Stability of Cu

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Zhang，Synthesis of highly dispersed MnOx–CeO2 nanospheres by surfactant-assisted supercritical anti-solvent (SAS) technique:

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Ordered mesoporous carbon supported ferric sulfate: A novel catalyst for the esterification of free fatty acids in waste cook

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Synthesis of highly efficient MnOx catalyst for low-temperature NH3-SCR prepared from Mn-MOF-74 template

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Controllable synthesis of Ce1-xZrxO2 hollow nanospheres via supercritical anti-solvent precipitation

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Hollow MnOx-CeO2 nanospheres prepared by a green route: A novel low-temperature NH3-SCR catalyst

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Preparation and evaluation of MnOx-CeO2 nanospheresvia a green route

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The action mechanism of ethanol in preparation of supported nano-sized Rucatalyst via supercritical fluid deposition

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Synthesis of MnOx-CeO2 NOx catalysts by polyvinylpyrrolidone-assisted supercritical antisolvent recipitation

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Catalytic Performance of Biomass Carbon-Based Solid Acid Catalyst for Esterification of Free Fatty Acids in Waste Cooking Oil

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High activity ordered mesoporous carbon-based solid acid catalyst for the esterification of free fatty acids

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Phosphorylated ordered mesoporous carbon as a novel solid acid catalyst for the esterification of oleic acid

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Investigation on Process Mechanism on Cu-Cr Catalysts for Ethanol Dehydrogenation to Ethyl Acetate

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Preparation and haracteristics of nano-crystalline Cu-Ce-Zr-O composite oxides via a green route: supercritical anti-solvent

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Structures and oxygen storage capacities of CeO2-ZrO2-Al2O3 ternary oxides prepared by a green route: supercritical anti-sol

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Temperature effect on the morphology and catalytic performance of Co-MOF-74 in low-temperature NH3-SCR process

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Preparation and formation mechanism of nano-sized MnOx-CeO2 hollow spheres via a supercritical anti-solvent technique

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Study on MnOx-FeOy composite oxide catalysts prepared by supercritical antisolvent process for low-temperature selective cata

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Hollow nano-particles formation for CuO-CeO2-ZrO2 via a supercritical anti-solvent process

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Enhanced oxygen storage capacity of Ce0.88Mn0.12Oy compared to CeO2: An experimental and theoretical investigation

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超临界抗溶剂法纳米Al2O3-ZrO2 颗粒的制备与表征

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Syntheses of Composite Oxide Catalyst via Supercritical Antisolvent Process

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High Dispersion of Metal on Carbon Support via Supercritical Fluid Assistance and its Catalytic Performance