摘要/Abstract

在化学领域，大自然一直是灵感的主要来源，是设计性能卓越材料的模仿对象.作者总结了借鉴仿生理念，以多孔有机聚合物（POPs）为设计平台构建高效催化体系.为此，首先从化学角度描述酶的结构特点以及要实现这些性质POPs的构建需求.然后举例介绍了使用POPs解决仿生催化相关的基本科学问题，并展示其巨大的应用潜力.最后，总结并提出了这个新兴领域面临的挑战和机遇.
关键词: 多孔有机聚合物, 仿生设计, 次级作用, 柔性骨架, 浸润性调控
Nature has served as a dominant source of inspiration in the area of chemistry, serving as prototypes for the design of materials with proficient performance. In this account, we present our effort to explore porous organic polymers (POPs) as a platform for the construction of biomimetic catalysts to enable new technologies to achieve efficient conversions. For each aspect, we firstly describe the chemical basis of nature, followed by presenting the principles and design strategies involved for functionalizing POPs along with a summary of critical requirements for materials, culminating in a demonstration of unique features of POPs. Our endeavors of using POPs to address the fundamental scientific problems related to biomimetic catalysis are then presented to show their enormous potential and capabilities for a wide range of catalytic transformations. To conclude, a personal perspective on the challenges and opportunities in this emerging field are presented.
Key words: porous organic polymers, biomimetic design, secondary interaction, flexible framework, wettability control


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